STUDIES ON THE CONSTITUENTS OF SCUTELLARIA SPECIES .15. ON THE DITERPENOID CONSTITUENTS OF THE LEAVES OF SCUTELLARIA-ALPINA L

被引：13
|
作者：
MIYAICHI, Y [1 ]
KIZU, H [1 ]
YAMAGUCHI, Y [1 ]
TOMIMORI, T [1 ]
机构：
[1] HOKURIKU UNIV, FAC PHARMACEUT SCI, KANAZAWA 92011, JAPAN
来源：
YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN | 1994年 / 114卷 / 04期
关键词：
SCUTELLARIA ALPINA; LABIATAE; NEOCLERODANE DITERPENOID; STRUCTURE ELUCIDATION;
D O I：
10.1248/yakushi1947.114.4_264
中图分类号：
R9 [药学];
学科分类号：
1007 ;
摘要：
From the leaves of Scutellaria alpina L., four new neo-clerodane diterpenes (1-4) were isolated. The structures of 1-4 were shown to be (4S)-19-acetoxy-8 beta-hydroxy-6 alpha-benzoyloxy-4,18-epoxy-neo-cleroda-11,13-dien-15,16-olide, (4S)-19-acetoxy-8 beta-hydroxy-6 alpha-tigloyloxy-4,18-epoxy-neo-cleroda-11,13- dien-15,16-olide, (4S, 11S)-11-acetoxy-8 beta,19-dihydroxy-6 alpha-tigloyloxy-4,18-epoxy-neo-clerod-13-en-15,16-olide, and (4S)-19-acetoxy-8 beta-hydroxy-6 alpha,7 beta-dibenzoyloxy-4,18-epoxy-neo-cleroda-11,13-dien-15,16-olide, respectively, by the chemical and spectral data.
引用
收藏
页码：264 / 271
页数：8
相关论文
共 50 条
  • [31] STUDIES ON THE CONSTITUENTS OF UMBELLIFERAE PLANTS .15. CONSTITUENTS OF CNIDIUM-OFFICINALE - OCCURRENCE OF PREGNENOLONE, CONIFERYLFERULATE AND HYDROXYPHTHALIDES
    KOBAYASHI, M
    FUJITA, M
    MITSUHASHI, H
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1987, 35 (04) : 1427 - 1433
  • [32] STUDIES ON THE CONSTITUENTS OF CUCURBITACEAE PLANTS .15. ON THE SAPONIN CONSTITUENTS OF GYNOSTEMMA-PENTAPHYLLUM MAKINO .10.
    YOSHIKAWA, K
    TAKEMOTO, T
    ARIHARA, S
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1986, 106 (09): : 758 - 763
  • [33] Studies on the constituents of the leaves of Morus alba L.
    Doi, K
    Kojima, T
    Makino, M
    Kimura, Y
    Fujimoto, Y
    CHEMICAL & PHARMACEUTICAL BULLETIN, 2001, 49 (02) : 151 - 153
  • [34] CONSTITUENTS OF IVA SPECIES .15. RELATIVE AND ABSOLUTE-CONFIGURATION OF PSEUDOIVALIN
    ANDERSON, GD
    GITANY, R
    MCEWEN, RS
    HERZ, W
    TETRAHEDRON LETTERS, 1973, (26) : 2409 - 2412
  • [35] CONSTITUENTS OF ECBALLIUM ELATERIUM L .15. STRUCTURES OF ELATERICIN A AND RELATED CUCURBITACINS
    LAVIE, D
    GOTTLIEB, OR
    GLOTTER, E
    SHVO, Y
    JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (12): : 4546 - &
  • [36] Studies on phytochemicals .15. Investigation on the alkaloidal constituents of Indian Mappia foetida
    Das, B
    Rao, SP
    Kashinatham, A
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1997, 36 (02): : 208 - 210
  • [37] STUDIES ON THE NEPALESE CRUDE DRUGS .13. ON THE FLAVONOID AND IRIDOID CONSTITUENTS OF THE ROOT OF SCUTELLARIA-GROSSA WALL
    KIKUCHI, Y
    MIYAICHI, Y
    TOMIMORI, T
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1991, 39 (04) : 1051 - 1054
  • [38] STUDIES ON CONSTITUENTS IN WATER EXTRACTS OF CRUDE DRUGS .1. ROOTS OF SCUTELLARIA-BAICALENSIS GEORGI (WOGON)
    TAKIDO, M
    AIMI, M
    TAKAHASHI, S
    YAMANOUCHI, S
    TORII, H
    DOHI, S
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1975, 95 (01): : 108 - 113
  • [39] STUDIES ON CONSTITUENTS OF FORMOSAN LEGUMINOSAE .1. CONSTITUENTS IN LEAVES OF CLITORIA-TERNATEA L
    MORITA, N
    ARISAWA, M
    NAGASE, M
    HSU, HY
    CHEN, YP
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1977, 97 (06): : 649 - 653
  • [40] STUDIES ON CONSTITUENTS OF USEFUL PLANTS .7. CONSTITUENTS OF LEAVES OF CASSIA-OBTUSIFOLIA L
    MATSUURA, S
    YOSHIOKA, S
    IINUMA, M
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1978, 98 (09): : 1288 - 1291
12345