SCANDIUM TRIFLUOROMETHANESULFONATE (SC(OTF)3) - A NOVEL REUSABLE CATALYST IN THE DIELS-ALDER REACTION

被引：205
|
作者：
KOBAYASHI, S
HACHIYA, I
ARAKI, M
ISHITANI, H
机构：
[1] Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Shinjuku-ku, Tokyo, 162, Kagurazaka
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 23期
关键词：
D O I：
10.1016/S0040-4039(00)79220-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Scandium trifluoromethanesulfonate (Sc(OTf)3) is found to be quite effective as a Lewis acid catalyst in the Diels-Alder reaction. The novel catalyst is available in both aqueous and organic media, is easily recovered from aqueous layer after the reaction is completed, and can be reused.
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页码：3755 / 3758
页数：4
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