ALTERNATIVE CONCEPT OF THE TRANSITION EMERALDINE BASE EMERALDINE SALT

被引：27
|
作者：
GOSPODINOVA, N
MOKREVA, P
TERLEMEZYAN, L
机构：
[1] Institute of Polymers, Bulgarian Academy of Sciences
来源：
POLYMER | 1993年 / 34卷 / 06期
关键词：
POLYANILINE; POLYANILINE DISPERSION; EMERALDINE BASE-EMERALDINE SALT TRANSITION;
D O I：
10.1016/0032-3861(93)90796-D
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The transition of the emeraldine base (EB) to the emeraldine salt (ES) form of polyaniline (PANI) is in fact a redox process [GRAPHICS] where 'EB' does not represent the emeraldine oxidation state. This redox process itself is an intermediate stage in the transition of insulating pernigraniline to conducting emeraldine. Generally, transition of PANI from insulating (leucoemeraldine, L, or pernigraniline, PN) to conducting (emeraldine, E) state could be represented by the following scheme:(~)[GRAPHICS]
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收藏
页码：1330 / 1332
页数：3
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