INTERMEDIATES FOR PHOTOISOMERIZATION OF A BUTENYLNAPHTHALENE IN THE PRESENCE OF ELECTRON-ACCEPTORS AS STUDIED BY SOLVENT DEPENDENCE OF MAGNETIC-FIELD EFFECTS

被引：1

作者：

NAITOH, K

OGUCHI, T

NAKAGAKI, R

ARAI, T

SAKURAGI, H

TOKUMARU, K

NAGAKURA, S

机构：

[1] UNIV TSUKUBA, DEPT CHEM, TSUKUBA, IBARAKI 305, JAPAN

[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 06期

关键词：

D O I：

10.1246/cl.1992.1077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The external magnetic field effect as well as laser flash photolysis was employed to estimate die contribution of ion radical pairs to isomerization of trans-2-(3,3-dimethyl-1-butenyl)naphthalene (t-BN) in the presence of an electron acceptor in various solvents. The precursor of isomerization, t-BN triplet, was produced most efficiently almost through an exciplex in chloroform (epsilon=4.8) among the employed solvents.

引用

页码：1077 / 1080

页数：4

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