OXIDATION OF ACTIVATED PHENOLS BY DIOXYGEN CATALYZED BY THE H5PV2MO10O40 HETEROPOLYANION

被引：73
|
作者：
LISSEL, M [1 ]
DEWAL, HJI [1 ]
NEUMANN, R [1 ]
机构：
[1] HEBREW UNIV JERUSALEM,GRAD SCH APPL SCI & TECHNOL,CASALI INST APPL CHEM,IL-91904 JERUSALEM,ISRAEL
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 13期
关键词：
HETEROPOLYANIONS; PHENOL OXIDATION; DIOXYGEN;
D O I：
10.1016/S0040-4039(00)91735-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.
引用
收藏
页码：1795 / 1798
页数：4
相关论文
共 50 条
  • [31] Combining Two into One: A Dual-Function H5PV2Mo10O40 @MOF-808 Composite as a Versatile Decontaminant for Sulfur Mustard and Soman
    Zhou, Yuanyuan
    Gao, Qi
    Zhang, Lijuan
    Zhou, Yunshan
    Zhong, Yuxu
    Yu, Jialin
    Liu, Jie
    Huang, Chengcheng
    Wang, Yong'An
    INORGANIC CHEMISTRY, 2020, 59 (16) : 11595 - 11605
  • [32] Catalytic aerobic oxidation of carbohydrates to formic acid over H5PV2Mo10O40: Rate relationships among catalyst reduction, catalyst re-oxidation and acid-catalyzed reactions and evidence for the Mars-van Krevelen mechanism
    He, Zhuosen
    Hou, Yucui
    Li, He
    Wei, Jian
    Ren, Shuhang
    Wu, Weize
    CHEMICAL ENGINEERING SCIENCE, 2023, 280
  • [33] Solid-State Crystal-to-Crystal Phase Transitions and Reversible Structure-Temperature Behavior of Phosphovanadomolybdic Acid, H5PV2Mo10O40
    Barats-Damatov, Delina
    Shimon, Linda J. W.
    Feldman, Yishay
    Bendikov, Tatyana
    Neumann, Ronny
    INORGANIC CHEMISTRY, 2015, 54 (02) : 628 - 634
  • [34] Oxidative dehydrogenation of 4-vinylcyclohexene to styrene catalyzed by PV2Mo10O5-40 heteropolyacids
    Neumann, R
    Dror, I
    APPLIED CATALYSIS A-GENERAL, 1998, 172 (01) : 67 - 72
  • [35] Mixed-addenda 10-molybdo-2-vanadophosphoric heteropolyacid (H5PV2Mo10O40):: An efficient catalyst under solvent-free conditions for rapid acylation of alcohols
    Farhadi, Saeid
    Taherimehr, Masoumeh
    CATALYSIS COMMUNICATIONS, 2008, 9 (05) : 703 - 708
  • [36] H5PV2Mo10O40 encapsulated in MIL-101(Cr): facile synthesis and characterization of rationally designed composite materials for efficient decontamination of sulfur mustardt
    Li, Yanqin
    Gao, Qi
    Zhang, Lijuan
    Zhou, Yunshan
    Zhong, Yuxu
    Ying, Ying
    Zhang, Mingcai
    Huang, Chunqian
    Wang, Yong'an
    DALTON TRANSACTIONS, 2018, 47 (18) : 6394 - 6403
  • [37] Aerobic oxidative dehydrogenations catalyzed by the mixed-addenda heteropolyanion PV2Mo10O405-. A kinetic and mechanistic study
    1600, (114):
  • [38] OXYBROMINATION CATALYZED BY THE HETEROPOLYANION COMPOUND H5PMO10V2O40 IN AN ORGANIC MEDIUM - SELECTIVE PARA-BROMINATION OF PHENOL
    NEUMANN, R
    ASSAEL, I
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (19) : 1285 - 1287
  • [39] Ag5PV2Mo10O40, a heterogeneous catalyst for air-based selective oxidation at ambient temperature
    Rhule, JT
    Neiwert, WA
    Hardcastle, KI
    Do, BT
    Hill, CL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (48) : 12101 - 12102
  • [40] Heterogeneous catalysis for air-based selective oxidation by Ag5PV2Mo10O40 at ambient temperature.
    Neiwert, WA
    Rhule, JT
    Hardcastle, KI
    Do, BT
    Hill, CL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U713 - U713
12345