STRUCTURE OF (AD,BE-BIS[(8-DIMETHYLAMINO-KAPPA-N)NAPHTHYL-KAPPA-C1])-F-ETHYL-C-IODOPLATINUM(IV)

被引：2
|
作者：
SMEETS, WJJ
SPEK, AL
VANBEEK, JAM
VANKOTEN, G
机构：
[1] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES,VAKGRP KRISTAL & STRUCT CHEM,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS
[2] UNIV UTRECHT,DEBYE RES INST,DEPT MET MEDIATED SYNTH,3584 CH UTRECHT,NETHERLANDS
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270192001616
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Pt(C12H12N)2(C2H5)I], M(r) = 691.5 1, monoclinic, P2(1)/n, a = 14.902 (1), b = 10.815 (4), c = 14.941 (1) angstrom, beta = 103.29 (1)-degrees, V = 2343.3 (3) angstrom3, Z = 4, D(x) = 1.960 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 73.7 cm -1, F(000) = 1320, T = 294 K, R = 0.030 for 4204 unique observed diffractometer data with I > 2.5-sigma(I). The platinum(IV) cation is coordinated by two C,N-chelate bonded 8-dimethylamino-1-naphthyl (dman) monoanionic ligands as well as the ethyl and iodo anions which are mutually in cis orientation. As oxidative addition reactions of primary alkyl halides to organometal-d8 complexes generally yield trans-(alkyl)(halide) products, the observed formation of the cis isomer in the reaction of Pt(dman)2 with EtI is an exception: the reaction with MeI affords the trans-(Me)(I) product.
引用
收藏
页码：1303 / 1305
页数：3
相关论文
共 50 条
  • [31] Crystal structure of bis(3,5-diisopropyl-1H-pyrazol-4-ammonium) tetrafluoroterephthalate, 2[C9H18N3][C8F4O4]
    Fujisawa, Kiyoshi
    Harakuni, Seigo
    Iwai, Kako
    Ageishi, Keigo
    Tiekink, Edward R. T.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (02): : 167 - 170
  • [32] The crystal structure of 6,6′-(((2-(dimethylamino) ethyl)azanediyl)bis(methylene))bis(benzo[d][1,3] dioxol-5-ol ato-κ4N,N′,O,O′)-(pyridine-2,6-dicarboxylato-N,O,O′)-titanium(IV)-dichloromethane(1/1), C27H25N3O10Ti
    Li, Shanjia
    Wang, Peng
    Ji, Mingyu
    Yang, Mingjun
    Pu, Xiuying
    Zhao, Tiankun
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (06): : 1165 - 1167
  • [33] Crystal structure of poly[bis(1,4-di(1H-imidazol-1-yl)butane-κ2N:N′) zinc(II)]bis(hexafluoridophosphate), C20H28F12N8P2Zn
    Zhu, Xia
    Guo, Ying
    Li, Jian-Gang
    Yang, Kun
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2013, 228 (04): : 459 - 460
  • [34] On the chemistry of fluoroorgano derivatives of group 13 elements.: 2 Synthesis and characterization of the 1:1-adducts of In(C6F5)3 with acetonitrile, glyme, and DMAP (DMAP=4-(N,N-dimethylamino)-pyridine), and [PNP][In(C6F5)4] (PNP = bis(triphenylphosphinanyliden)-immonium) -: The crystal structure of [PNP[In(C6F5)4]
    Choi, ZH
    Tyrra, W
    Adam, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (08): : 1287 - 1292
  • [35] Crystal structure of 1,1′-(hexane-1,6-diyl)bis(3-ethyl-1H-imidazol-3-ium) bis(hexafluorido phosphate), C16H28F12N4P2
    Wen, Zhao
    Jing, Chen
    Wan-Ming, Xiong
    Ying-Dong, Lan
    Xu-Liang, Nie
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (04): : 609 - 611
  • [36] Crystal structure of 1,1′-(ethane-1,2-diyl)bis (3-ethyl-1H-imidazol-3-ium)bis(hexafluorido phosphate), C12H20F12N4P2
    Xiong Wan-Ming
    Di Yi-Bo
    Lan Ying-Dong
    Chen Jing
    Nie Xu-Liang
    Huang Chang-Gan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (02): : 201 - 203
  • [37] Crystal structure of diaqua-bis(1,10-phenanthroline κ2N,N′)nickel(II) trifluoroacetate-trifluoroacetic acid (1/1), C30H21F9N4NiO8
    Zhang, Lan
    Wang, Qiang
    Ding, Wu-Xiu
    Hao, Hui-Min
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (05): : 869 - 871
  • [38] Crystal structure of 1,1′-(butane-1,4-diyl) bis(3-propyl-1H-imidazol-3-ium) bis(hexafluoridophosphate), C32H56F24N8P4
    Zhou, Yao-Hong
    Nie, Xu-Liang
    Xiong, Wan-Ming
    Peng, Da-Yong
    Zhang, Xiao-Hua
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (05): : 1105 - 1107
  • [39] UNEXPECTED FORMATION AND X-RAY STRUCTURE OF TETRAMETHYL 4,5-BIS(DIMETHYLAMINO)-2,3,6,7-TETRA-AZAOCTA-1,3,5,7-TETRAENE-1,1,8,8-TETRACARBOXYLATE [C16H24N6O8] FROM BIS(DIMETHYLAMINO)ACETYLENE AND DIMETHYL DIAZOMALONATE
    TINANT, B
    DECLERCQ, JP
    VANMEERSSCHE, M
    BOUVY, A
    JANOUSEK, Z
    VIEHE, HG
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (09): : 1419 - 1421
  • [40] DI-MU-BROMO-3-3'KAPPA-BR-4-BIS[MU-(2-PHENYL-3-PHENYLAMINO-3-SULFIDO-2-AZONIAPROP-2-EN-1-YL-3-KAPPA-S-8-KAPPA-C-1)-1,2-DICARBA-3-RHODA-CLOSO-DODECABORANE], A NOVEL DIMERIC METALLACARBORANE CONTAINING A RH2BR2 BRIDGING SECTION AND THE (-SC(NHPH)-N(PH)CH2-) LIGAND
    FERGUSON, G
    SPALDING, TR
    MCENEANEY, PA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 1501 - 1503
12345