RHODIUM-CATALYZED MODIFICATION OF POLY(METHYLHYDROSILOXANE) INTO A HIGHLY CROSS-LINKED POLYSILOXANE

被引：16
|
作者：
SATYANARAYANA, N [1 ]
ALPER, H [1 ]
机构：
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA
来源：
MACROMOLECULES | 1995年 / 28卷 / 01期
关键词：
D O I：
10.1021/ma00105a038
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Rhodium-catalyzed modification of poly(methylhydrosiloxane) (PMHS) via a dehydrogenative coupling reaction followed by in-situ oxidation under mild conditions gives a thermally stable and crosslinked polysiloxane. The polysiloxane was characterized by solid state Si-29 NMR spectroscopy.
引用
收藏
页码：281 / 283
页数：3
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