HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL BARIUM VANADIUM-OXIDE - BA0.4V3O8(VO)(0.4)CENTER-DOT-NH2O

被引：17

作者：

OKA, Y

TAMADA, O

YAO, T

YAMAMOTO, N

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,KYOTO 606,JAPAN

[2] KYOTO UNIV,GRAD SCH HUMAN & ENVIRONM STUDIES,KYOTO 606,JAPAN

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 114卷 / 02期

关键词：

D O I：

10.1006/jssc.1995.1055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new barium vanadium oxide Ba0.4V3O8(VO)(0.4) . nH(2)O (n similar to 0.6) has been synthesized hydrothermally from a VOCl2-BaCl2 solution. The green-black crystal composed of elongated thin plates exhibits a monoclinic system: P2(1)/m, a = 10.153(3) Angstrom, b = 3.6329(9) Angstrom, c = 9.435(2) Angstrom, and beta = 102.10(2)degrees. Structural analysis using 951 independent reflections led to R = 0.063 and R(w) = 0.076. The structure is basically a layered type made up of V3O8 layers with interstitial Ba2+ ions and water molecules. Its striking feature is that the V3O8 layers are bridged imperfectly by partially absent VO5 trigonal bipyramids which form tunnel-like openings. The structure is thus regarded as an intermediate between layered and tunnel structure types. Interstitial Ba2+ ions were observed to be displaced from the position on the mirror plane. (C) 1995 Academic Press, Inc.

引用

页码：359 / 363

页数：5

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