METHYL FORMATE SYNTHESIS BY HYDROGENATION OF SUPERCRITICAL CARBON-DIOXIDE IN THE PRESENCE OF METHANOL

被引：68
|
作者：
JESSOP, PG
HSIAO, Y
IKARIYA, T
NOYORI, R
机构：
[1] RES DEV CORP JAPAN,ERATO MOLEC CATALYSIS PROJECT,TOYOTA 47003,JAPAN
[2] NAGOYA UNIV,DEPT CHEM,NAGOYA,AICHI 46401,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期
关键词：
D O I：
10.1039/c39950000707
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Addition of methanol in the homogeneous ruthenium-catalysed hydrogenation of supercritical carbon dioxide to formic acid results in thermal esterification, producing methyl formate in higher yields and at lower temperatures than previously reported.
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页码：707 / 708
页数：2
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