METHYL FORMATE SYNTHESIS BY HYDROGENATION OF SUPERCRITICAL CARBON-DIOXIDE IN THE PRESENCE OF METHANOL

被引：68

作者：

JESSOP, PG

HSIAO, Y

IKARIYA, T

NOYORI, R

机构：

[1] RES DEV CORP JAPAN,ERATO MOLEC CATALYSIS PROJECT,TOYOTA 47003,JAPAN

[2] NAGOYA UNIV,DEPT CHEM,NAGOYA,AICHI 46401,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of methanol in the homogeneous ruthenium-catalysed hydrogenation of supercritical carbon dioxide to formic acid results in thermal esterification, producing methyl formate in higher yields and at lower temperatures than previously reported.

引用

页码：707 / 708

页数：2

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