Comparison of the FT Raman spectra of inorganic tetrahedral ions over the temperature range 77 to 473 K

被引:16
|
作者
Pope, SJA [1 ]
West, YD [1 ]
机构
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND
关键词
D O I
10.1016/0584-8539(95)01509-1
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The vibrational spectra recorded over a wide temperature range (77-473 K) of a number of inorganic transition metal salts containing tetraoxyanions in both solution and crystal phases are reported. All modes in these cases are Raman active and the bands predicted by site-symmetry analysis are observed. Only bands assigned as nu(3) and nu(1) are found to be temperature dependent. The significance of this is discussed.
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页码:2027 / 2037
页数:11
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