SYNTHESIS AND CRYSTAL-STRUCTURE OF CESIUM-LITHIUM CYCLOHEXAPHOSPHATE DIHYDRATE

被引：1

作者：

ELMOKHTAR, OSM ^{[1
]}

RZAIGUI, M ^{[1
]}

SAID, H ^{[1
]}

AVERBUCHPOUCHOT, MT ^{[1
]}

DURIF, A ^{[1
]}

机构：

[1] UNIV GRENOBLE 1, CRISTALLOG LAB, CNRS, F-38042 GRENOBLE 09, FRANCE

来源：

MATERIALS RESEARCH BULLETIN | 1995年 / 30卷 / 08期

关键词：

CESIUM; LITHIUM; PHOSPHATE;

D O I：

10.1016/0025-5408(95)00072-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Cs(3)Li(3)P(6)O(18)2H(2)O is triclinic, <P(1)over bar>, with Z = 1 and the following unit-cell dimensions: a = 7.938 (2), b = 7.674 (2), c = 9.556 (2), alpha = 113.39 (4), beta = 93.83 (4), gamma = 83.00 (4). The crystal structure was determined using 4,576 reflections leading to a final R value of 0.022. The atomic arrangement of this new cyclohexa-phosphate exhibits several unusual features of disorder affecting both cations and water molecules.

引用

页码：1049 / 1054

页数：6

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