SYNTHESIS AND CRYSTAL-STRUCTURE OF CESIUM-LITHIUM CYCLOHEXAPHOSPHATE DIHYDRATE

被引：1
|
作者：
ELMOKHTAR, OSM [1 ]
RZAIGUI, M [1 ]
SAID, H [1 ]
AVERBUCHPOUCHOT, MT [1 ]
DURIF, A [1 ]
机构：
[1] UNIV GRENOBLE 1, CRISTALLOG LAB, CNRS, F-38042 GRENOBLE 09, FRANCE
来源：
MATERIALS RESEARCH BULLETIN | 1995年 / 30卷 / 08期
关键词：
CESIUM; LITHIUM; PHOSPHATE;
D O I：
10.1016/0025-5408(95)00072-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Cs(3)Li(3)P(6)O(18)2H(2)O is triclinic, <P(1)over bar>, with Z = 1 and the following unit-cell dimensions: a = 7.938 (2), b = 7.674 (2), c = 9.556 (2), alpha = 113.39 (4), beta = 93.83 (4), gamma = 83.00 (4). The crystal structure was determined using 4,576 reflections leading to a final R value of 0.022. The atomic arrangement of this new cyclohexa-phosphate exhibits several unusual features of disorder affecting both cations and water molecules.
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收藏
页码：1049 / 1054
页数：6
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