PHOTOSENSITIZED DECHLORINATION OF POLYCHLORINATED PHENOLS .1. CARBAZOLE-PHOTOSENSITIZED DECHLORINATION OF PENTACHLOROPHENOL

被引：16
|
作者：
NOWAKOWSKA, M
SZCZUBIALKA, K
机构：
[1] Faculty of Chemistry, Jagiellonian University, 30-060 Kraków
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1995年 / 91卷 / 01期
关键词：
CARBAZOLE; DECHLORINATION; ELECTRON TRANSFER; FLUORESCENCE QUENCHING; PENTACHLOROPHENOL; PHOTOCHEMICAL REACTION;
D O I：
10.1016/1010-6030(95)04109-S
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The dechlorination of pentachlorophenol (PCP) photosensitized by carbazole (Cz) has been studied. It is shown that 2,3,4,5,-tetrachlorophenol (TCP) is the main primary product. Prolonged irradiation results in the formation of trichlorophenols. The process is explained via a mechanism involving electron transfer from excited Ct to PCP.
引用
收藏
页码：81 / 85
页数：5
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