THE ADSORPTION OF NO2 ON AG(111) - A LOW-TEMPERATURE RAIRS STUDY

被引：34

作者：

BROWN, WA ^{[1
]}

GARDNER, P ^{[1
]}

KING, DA ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

来源：

SURFACE SCIENCE | 1995年 / 330卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0039-6028(95)00397-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Initial adsorption of NO2 on Ag(111) at 86 K is dissociative and gives rise to the formation of adsorbed O and (NO)(2) dimers. Subsequent adsorption is complex leading to the formation of NO3, NO and N2O3 which coexist on the surface with the O and (NO)(2). Further adsorption then leads to the formation of multilayers of N2O4. The multilayers are seen to desorb at 140 K, in agreement with previous observations.

引用

页码：41 / 47

页数：7

共 50 条

[21] RAIRS studies of CO adsorption on Pd/CeO2-x(111)/Pt(111)
Wilson, E. L.
Brown, W. A.
Thornton, G.
[J]. SURFACE SCIENCE, 2006, 600 (12) : 2555 - 2561
[22] Low-temperature reduction of NO2 on oxidized Mo(110)
Deiner, LJ
Kang, DH
Friend, CA
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (26): : 12826 - 12831
[23] Adsorption of CO on Pt{111}: a synchrotron far-infrared RAIRS study
Surman, M
Hagans, PL
Wilson, NE
Baily, CJ
Russell, AE
[J]. SURFACE SCIENCE, 2002, 511 (1-3) : L303 - L306
[24] A temperature dependent investigation of the adsorption of CO on Pt(111) using low-temperature single crystal adsorption calorimetry
Hoertz, Peter
Ruff, Philip
Schaefer, Rolf
[J]. SURFACE SCIENCE, 2015, 639 : 66 - 69
[25] LOW-TEMPERATURE ADSORPTION AND PHOTOCHEMICAL CHARACTERISTICS OF METHYL-BROMIDE ON PT(111)
FRENCH, C
HARRISON, I
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 330 - PHYS
[26] Effects of SO2 on NO adsorption and NO2 formation over TiO2 low-temperature SCR catalyst
Uddin, Md. Azhar
Ishibe, Koji
Wu, Shengji
Su, Caili
Sasaoka, Eiji
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (06) : 1672 - 1676
[27] NO2 dissociation on Ag(111) revisited by theory
Hellman, Anders
Panas, Itai
Groenbeck, Henrik
[J]. JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (10):
[28] Thermal chemistry of CF3I on Ag(111): A TPD and RAIRS study
Szabo, A
Converse, SE
Whaley, SR
White, JM
[J]. SURFACE SCIENCE, 1996, 364 (03) : 345 - 366
[29] THE ADSORPTION OF NO2 ON PT(111) STUDIED BY TEMPERATURE PROGRAMMED DESORPTION AND VIBRATIONAL SPECTROSCOPY
BARTRAM, ME
WINDHAM, RG
KOEL, BE
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 55 - COLL
[30] LOW-TEMPERATURE ADSORPTION AND REACTION OF O-2 WITH SI(111)7X7
SCHELLSOROKIN, AJ
DEMUTH, JE
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1985, 3 (03): : 1475 - 1476

← 1 2 3 4 5 →