RELATIONSHIP BETWEEN CHARGE-TRANSFER RESISTANCE AND EXCHANGE CURRENT-DENSITY OF ION TRANSFER AT THE INTERFACE OF 2 IMMISCIBLE ELECTROLYTE-SOLUTIONS

被引：22

作者：

HORVAI, G

机构：

[1] Technical University, Institute for General and Analytical Chemistry, Budapest, H-1111

来源：

ELECTROANALYSIS | 1991年 / 3卷 / 07期

关键词：

D O I：

10.1002/elan.1140030713

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A simple derivation shows the validity of the reciprocal relation between charge transfer resistance and exchange current density. The result is independent of the equation used for estimating the potential difference across the space charge region. Butler-Volmer kinetics with Frumkin correction or the Verwey-Niessen model (i.e. Frumkin correction only) lead to the same result.

引用

页码：673 / 675

页数：3

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