BIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES OF PALLADIUM AS CATALYSTS FOR HYDROSILYLATION OF OLEFINS BY TRICHLOROSILANE

被引：6

作者：

GULINSKI, J ^{[1
]}

JAMES, BR ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 72卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0304-5102(92)80042-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mononuclear Pd(II), and dinuclear Pd(O) and Pd(I) complexes containing bis(diphenylphosphino)methane catalyze the addition of trichlorosilane to the olefinic bond of hexene-1, styrene and vinyltrichlorosilane. Activity relationships for limited data at 80 and 120-degrees-C suggest that in each case mononuclear Pd(O) species might act as a catalyst precursor.

引用

页码：167 / 171

页数：5

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