ORGANOMANGANESE REAGENTS .30. ENANTIOSELECTIVE PREPARATION OF ALPHA-ACYLOXY KETONES FROM ALPHA-HYDROXY AND ALPHA-AMINO-ACIDS

被引：28

作者：

CAHIEZ, G

METAIS, E

机构：

[1] Laboratoire de Chimie, Organoéléments (associé au CNRS) Université P. et M. Curie, F-75252 Paris Cédex 05

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 36期

关键词：

D O I：

10.1016/0040-4039(95)01289-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various chiral alpha-acyloxy ketones have been easily prepared, in high yields with an excellent enantiomeric purity, by acylation of organomanganese reagents with the corresponding alpha-acyloxy carboxylic acid chlorides prepared from alpha-hydroxy and alpha-amino acids.

引用

页码：6449 / 6452

页数：4

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