ORGANOMANGANESE REAGENTS .30. ENANTIOSELECTIVE PREPARATION OF ALPHA-ACYLOXY KETONES FROM ALPHA-HYDROXY AND ALPHA-AMINO-ACIDS

被引：28
|
作者：
CAHIEZ, G
METAIS, E
机构：
[1] Laboratoire de Chimie, Organoéléments (associé au CNRS) Université P. et M. Curie, F-75252 Paris Cédex 05
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 36期
关键词：
D O I：
10.1016/0040-4039(95)01289-T
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various chiral alpha-acyloxy ketones have been easily prepared, in high yields with an excellent enantiomeric purity, by acylation of organomanganese reagents with the corresponding alpha-acyloxy carboxylic acid chlorides prepared from alpha-hydroxy and alpha-amino acids.
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页码：6449 / 6452
页数：4
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