CRYSTAL AND MOLECULAR-STRUCTURES OF CESIUM PHENYLPENTACHLOROPLUMBATE AND TETRAMETHYLAMMONIUM PHENYLPENTACHLOROSTANNATE

被引：0
|
作者：
YATSENKO, AV
MEDVEDEV, SV
ASLANOV, LA
机构：
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 1989年 / 30卷 / 02期
关键词：
D O I：
10.1007/BF00761317
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An x-ray structural study of Cs2PhPbCl5 (I) and (NMe4)2PhSnCl5 (II) has been carried out to determine the regular features of the mutual influence of ligands in octahedral complexes of transition metals. The Sn-Cl and Pb-Cl bonds undergo cis-weakening under the influence of the phenyl group. trans-Strengthening is observed in Complex I, but not in complex II.
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页码：272 / 276
页数：5
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