THE PREPARATION OF (Z)-2-LITHIO-ORTHO-STYRYLLITHIUM VIA AN ORTHO-DIRECTED LITHIATION

被引：10
|
作者：
ASHE, AJ
SAVLA, PM
机构：
[1] Department of Chemistry, The University of Michigan, Ann Arbor
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 461卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)83263-U
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Lithiation of (Z)-2-lithiostyrene with t-butyllithium/TMEDA pentane led directly to (Z)-2-lithio-ortho-styryllithium. Subsequent treatment of this dilithio compound with difunctional electrophiles allowed the preparation of a variety of benzo[b]heteroles.
引用
收藏
页码：1 / 3
页数：3
相关论文
共 50 条
  • [1] Ortho-directed lithiation of ω-phenoxy alcohols
    Salteris, CS
    Kostas, ID
    Micha-Screttas, M
    Heropoulos, GA
    Screttas, CG
    JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (15): : 5589 - 5592
  • [2] ORTHO-DIRECTED LITHIATION IN PI-DEFICIENT DIAZINYL HETEROCYCLES
    MATTSON, RJ
    SLOAN, CP
    JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (10): : 3410 - 3412
  • [3] ORTHO-DIRECTED LITHIATION IN PI-DEFICIENT DIAZINYL HETEROCYCLES
    SLOAN, CP
    MATTSON, RJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 92 - ORGN
  • [4] Ortho-directed lithiation of 3,4-(alkylenedioxy)halobenzenes with LDA and LiTMP. The first ortho lithiation of an iodobenzene
    Mattson, RJ
    Sloan, CP
    Lockhart, CC
    Catt, JD
    Gao, Q
    Huang, S
    JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (21): : 8004 - 8007
  • [5] SYNTHESIS OF 5-SUBSTITUTED PYRIMIDINES THROUGH ORTHO-DIRECTED LITHIATION REACTIONS
    WADA, A
    YAMAMOTO, J
    KANATOMO, S
    HETEROCYCLES, 1987, 26 (03) : 585 - 589
  • [6] Ortho-directed lithiation of 3,4-alkylenedioxy-halobenzenes with LDA and LiTMP. The first ortho-lithiation of an iodo-benzene.
    Mattson, RJ
    Sloan, CP
    Lockhart, CC
    Catt, JD
    Gao, Q
    Huang, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U369 - U369
  • [7] SYNTHESIS OF 5-SUBSTITUTED PYRIMIDINES - ORTHO-DIRECTED LITHIATION OF PYRIMIDINE-DERIVATIVES
    WADA, A
    YAMAMOTO, J
    HAMAOKA, Y
    OHKI, K
    NAGAI, S
    KANATOMO, S
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1990, 27 (06) : 1831 - 1835
  • [8] ORTHO-DIRECTED LITHIATION OF (2-METHOXY)ETHOXY-ARENES AND (2-DIMETHYLAMINO)ETHOXY-ARENES
    WADA, A
    KANATOMO, S
    NAGAI, S
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1985, 33 (03) : 1016 - 1022
  • [9] ortho-Directed Dilithiation of Hexaphenyl-carbodiphosphorane
    Boettger, Silas C.
    Poggel, Christina
    Sundermeyer, Joerg
    ORGANOMETALLICS, 2020, 39 (21) : 3789 - 3793
  • [10] Directed ortho-Lithiation: Observation of an Unexpected 1-Lithio to 3-Lithio Conversion of 1-Lithio-naphthyllithium Compounds with an ortho-Directing 2-(Dimethylamino)methyl Group
    Jastrzebski, Johann T. B. H.
    Arink, Anne M.
    Kleijn, Henk
    Braam, Thijs W.
    Lutz, Martin
    Spek, Anthony L.
    van Koten, Gerard
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (36) : 13371 - 13378
12345