SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF MANGANESE(II), COBALT(II) AND ZINC(II) COMPLEXES OF ISONITROSOACETOPHENONE THIOSEMICARBAZONE AND ISONITROSO-4-CHLOROACETOPHENONE THIOSEMICARBAZONE

被引：0

作者：

SHETTI, SN

MURTY, ASR

TEMBE, GL

机构：

[1] KARNATAK UNIV,DEPT CHEM,DHARWAR 580003,KARNATAKA,INDIA

[2] INDIAN PETROCHEM CORP LTD,RES CTR,BARODA 391346,GUJARAT,INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1993年 / 32卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes of the formulae [MLCl3]Cl, [ML'Cl3]Cl (M = Ti); ML2 {where M = Mn(II), Co(II), Ni(II) and Zn(II); L = isonitrosoacetophenone thiosemicarbazone (INAPT) and L'= isonitroso-4-chloroacetophenone thiosemicarbazone} have been prepared and characterized on the basis of elemental analysis, conductance, magnetic moments, IR, electronic and NMR spectral data. In all the complexes the ligand is coordinated to the central metal ion through 'S' (>C = S)'N'(N-OH)after deprotonation and 'N'(C = N) as shown by IR and NMR spectral studies.

引用

页码：511 / 516

页数：6

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