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A NEW PALLADIUM-CATALYZED SYNTHESIS OF 3-SUBSTITUTED 2-ARYLIDEN-2,3-DIHYDRO-1H-INDEN-1-ONES
被引:14
|作者:
BROCATO, E
CASTAGNOLI, C
CATELLANI, M
CHIUSOLI, GP
机构:
[1] Instituto di Chimica Organica dell'Università, I-43100 Parma, Viale delle Science
关键词:
D O I:
10.1016/S0040-4039(00)60208-3
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Sequential oxidative additions of ortho-alkoxycarbonylmethylene or alkylamidomethylene-substituted aryl iodides, carbon monoxide insertion, reductive coupling with terminal alkynes, nucleophilic attack by the activated methylene group, and protonation with metal elimination afford the title compounds in a one-pot catalytic process.
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页码:7433 / 7436
页数:4
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