ENT-LABDANE AND NEOCLERODANE DITERPENES FROM GYMNOSPERMA-GLUTINOSUM

被引:9
|
作者
MALDONADO, E
SEGURACORREA, R
ORTEGA, A
CALDERON, JS
FRONCZEK, FR
机构
[1] UNIV NACL AUTONOMA MEXICO,INST QUIM,CIRCUIT EXTERIOR,MEXICO CITY,DF,MEXICO
[2] UNIV NACL COLOMBIA,DEPT QUIM,BOGOTA,COLOMBIA
[3] LOUISIANA STATE UNIV,DEPT CHEM,BATON ROUGE,LA 70803
关键词
GYMNOSPERMA GLUTINOSUM; COMPOSITAE; DITERPENES; ENT-LABDANE; NEOCLERODANE;
D O I
10.1016/S0031-9422(00)90594-6
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
From aerial parts of Gymnosperma glutinosum two new diterpenoids were isolated. Their structures were established as (+)-ent-labd-7-en-13S,14R,15-triol and (-)-17-hydroxy-neo-clerod-3-en-15-oic acid, by spectral means and chemical transformations. The structure of the labdane derivative was confirmed by X-ray diffraction analysis.
引用
收藏
页码:721 / 724
页数:4
相关论文
共 50 条
  • [41] ent-Labdane and ent-kaurane diterpenoids from Chelonopsis odontochila with α-glucosidase inhibitory activity
    Deng, Zhen-Tao
    Chen, Ji-Jun
    Geng, Chang-An
    BIOORGANIC CHEMISTRY, 2020, 95
  • [42] Nine new ent-labdane diterpenoids from the aerial parts of Andrographis paniculata
    Chen, Li-Xia
    Qiu, Feng
    Wei, Hong
    Qu, Ge-Xia
    Yao, Xin-Sheng
    HELVETICA CHIMICA ACTA, 2006, 89 (11) : 2654 - 2664
  • [43] Isolation and identification of ent-labdan diterpenes from the Mexican plant Gymnosperma glutinosum (Asteraceae) and cytotoxicity evaluation against murine lymphoma L5178Y-R
    Morado-Castillo, R.
    Quintanilla-Licea, R.
    Gomez-Flores, R.
    Blaschek, W.
    PLANTA MEDICA, 2014, 80 (16) : 1461 - 1462
  • [44] ENT-LABDANE DITERPENOIDS, TREMETONE AND CHROMENE DERIVATIVES AND FLAVONOIDS FROM OPHRYOSPORUS-HEPTANTHUS
    FERRACINI, VL
    ROEWER, I
    GAO, F
    MABRY, TJ
    PHYTOCHEMISTRY, 1989, 28 (05) : 1463 - 1465
  • [45] Three New ent-Labdane Diterpenoids from the Wood of Excoecaria agallocha LINN.
    Gowri, Ponnapalli Mangala
    Bhattar, Sri Vedavyasa Srirangaraja Radhakrishnan
    Reddy, Poreddy Guruva
    Rakesh, Yerraballi
    Basha, Shaik Jeelani
    Sarma, AkellaVenkata Subrahmanya
    Rao, Janaswamy Madhusudana
    HELVETICA CHIMICA ACTA, 2009, 92 (07) : 1419 - 1427
  • [46] Two new ent-labdane diterpenoid glycosides from the aerial parts of Andrographis paniculata
    Zhou, Kai-Lan
    Chen, Li-Xia
    Zhuang, Yu-Lei
    Wang, Nai-Li
    Yao, Xin-Sheng
    Qiu, Feng
    JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH, 2008, 10 (10) : 939 - 943
  • [47] Flavonoids and ent-labdane diterpenoids from Andrographis paniculata and their antiplatelet aggregatory and vasorelaxing effects
    Wu, Tian-Shung
    Chern, Huei-Jen
    Damu, Amooru Gangaiah
    Kuo, Ping-Chung
    Su, Chung-Ren
    Lee, E. -Jian
    Teng, Chi-Ming
    JOURNAL OF ASIAN NATURAL PRODUCTS RESEARCH, 2008, 10 (01) : 17 - 24
  • [48] Synthesis of new ent-labdane diterpene derivatives from andrographolide and evaluation on cytotoxic activities
    Luo, Yan
    Wang, Ke
    Zhang, Meng-han
    Zhang, Da-yong
    Wu, Yang-chang
    Wu, Xiao-ming
    Hua, Wei-yi
    BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2015, 25 (11) : 2421 - 2424
  • [49] Discovery of ent-labdane derivatives from Andrographis paniculata and their anti-inflammatory activity
    Yu, Yang
    Wang, Yang
    Ding, Lan
    Wang, Gui-Chun
    Geng, Hao
    Tan, Cheng-Yong
    Wang, Yi
    Liu, Jin-Song
    Wang, Guo-Kai
    PHYTOCHEMISTRY, 2024, 219
  • [50] Hypofolins A - L, ent-Labdane Diterpenoids from the Roots of Hypoestes phyllostachya "Pink Splash'
    Cheng, Bin
    Ding, Lin-Fen
    Yan, Tong
    Xie, Zhang-Qiao
    Zhang, Zhi-jun
    Song, Liu-Dong
    Wu, Xing-De
    Zhao, Qin-Shi
    CHEMISTRY & BIODIVERSITY, 2018, 15 (06)