ELECTROCHEMICAL STUDY ON MO(VI) AND CU(II) URONATES

被引:2
|
作者
STOJKOVSKI, S [1 ]
JAMES, BD [1 ]
PAYNE, R [1 ]
MAGEE, RJ [1 ]
机构
[1] LA TROBE UNIV,DEPT CHEM,BUNDOORA,VIC 3083,AUSTRALIA
关键词
D O I
10.1016/0162-0134(94)85121-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The Mo(VI)- and Cu(II)-binding properties of uronic acids at physiological pH have been examined by polarography. The metals have been confirmed to retain their original oxidation states on binding to the uronic acids and the molybdenum is most likely to be present in the form of an oxo-cation (Mo2O52+). These results support those obtained earlier by H-1 and C-13 NMR studies.
引用
收藏
页码:33 / 37
页数:5
相关论文
共 50 条
  • [31] NOVEL POLYSTYRENE-ANCHORED FE(III), CO(II), NI(II), CU(II), ZN(II), CD(II), MO(VI) AND U(VI) COMPLEXES OF THE CHELATING RESIN CONTAINING AN ON DONOR BIDENTATE SCHIFF-BASE
    SYAMAL, A
    SINGH, MM
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1993, 32 (05): : 431 - 434
  • [32] Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(vi) centres of Ru(ii)-Mo(vi) dyads†
    Pashaki, Maryam Nazari Haghighi
    Choi, Tae-Kyu
    Rohwer, Egmont J.
    Feurer, Thomas
    Duhme-Klair, Anne-Kathrin
    Gawelda, Wojciech
    Cannizzo, Andrea
    CHEMICAL COMMUNICATIONS, 2021, 57 (34) : 4142 - 4145
  • [33] An EXAFS study of Mo(VI) and Mo(V) complexes with proline dithiocarbamate
    Macías, B
    Malet, P
    Paradinas, R
    Rives, V
    Villa, MV
    INORGANICA CHIMICA ACTA, 1999, 288 (02) : 127 - 133
  • [34] Design and fabrication of novel coordination polymers containing Co(II), Ni(II), and Cu(II) for electrochemical detection of both ascorbic acid and Cr(VI)
    Li, Xiaohui
    Wang, Bingqian
    Gao, Yue
    Liu, Guocheng
    Wang, Xiuli
    TRANSITION METAL CHEMISTRY, 2023, 48 (05) : 307 - 314
  • [35] Design and fabrication of novel coordination polymers containing Co(II), Ni(II), and Cu(II) for electrochemical detection of both ascorbic acid and Cr(VI)
    Xiaohui Li
    Bingqian Wang
    Yue Gao
    Guocheng Liu
    Xiuli Wang
    Transition Metal Chemistry, 2023, 48 : 307 - 314
  • [36] ELECTROCHEMICAL STUDY OF U(VI) AND CR(VI) IN MOLTEN BORATES
    BRIGAUDEAU, M
    DEGREGORIDEPINOCHET, I
    ANALUSIS, 1977, 5 (02) : 55 - 61
  • [37] Study on adsorption of Cu(II)-Cr(VI) binary system by carbonized Eupatorium adenophorum
    Chen, Jinfa
    Song, Dagang
    Yang, Peng
    SEPARATION SCIENCE AND TECHNOLOGY, 2016, 51 (05) : 749 - 758
  • [38] SPECTROPHOTOMETRIC STUDY OF 2-PHENYLACETOHYDROXAMIC ACID CHELATES OF CU(II) AND DIOXOURANIUM(VI)
    REDDY, D
    SETHURAM, B
    RAO, TN
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1980, 19 (05): : 495 - 499
  • [39] REACTIVITY BETWEEN PHENYLBIGUANIDE HYDROCHLORIDE AND MO(VI), W(VI), V(V) AND NI(II)
    CALATAYUD, JM
    REIG, FB
    CARIDAD, MPF
    AFINIDAD, 1981, 38 (376) : 537 - 540
  • [40] MO(GS)MBE and photo-MO(GS)MBE of II-VI semiconductors
    Kyoto Univ, Kyoto, Japan
    J Cryst Growth, 1-4 (196-201):