PRECISE CONTROL OF POLYMER SYNTHESIS WITH A NEW CATALYST

被引：3
|
作者：
INOUE, S
机构：
[1] Department of Synthetic Chemistry, Faculty of Engineering, University of Tokyo, Tokyo 113, Hongo 7-3-1, Bunkyo-ku
来源：
PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES | 1991年 / 67卷 / 08期
关键词：
MACROMOLECULE; POLYMERIZATION; PORPHYRIN;
D O I：
10.2183/pjab.67.144
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Aluminum porphyrin is an excellent catalyst for the synthesis of polymers from a wide variety of monomers such as epoxide, lactone, and methacrylic ester, to give the polymers with controlled molecular weight. A novel catalyst system composed of aluminum porphyrin and an organoaluminum compound with bulky substituents brings about a remarkably accelerated reaction retaining the controlled molecular weight of the polymer.
引用
收藏
页码：144 / 147
页数：4
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