OPTICAL PULSE-RADIOLYSIS CELL AND APPARATUS DESIGNED TO STUDY REACTIONS IN SUPERCRITICAL FLUIDS

被引：11
|
作者：
ZHANG, JW [1 ]
CONNERY, KA [1 ]
STREBINGER, RB [1 ]
BRENNECKE, JF [1 ]
CHATEAUNEUF, JE [1 ]
机构：
[1] UNIV NOTRE DAME,RADIAT LAB,NOTRE DAME,IN 46556
来源：
REVIEW OF SCIENTIFIC INSTRUMENTS | 1995年 / 66卷 / 06期
关键词：
D O I：
10.1063/1.1145468
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
The details of the construction of a high-pressure optical cell and flow apparatus for the study of pulse-radiolytically induced reactions in supercritical fluids are described. Application of pulse radiolysis and time-resolved absorption spectroscopy to near-critical dense gas and supercritical fluid allows for the generation and investigation of ionic transient species in these low dielectric media. Methodologies for sample preparation and pulse radiolysis of supercritical mixtures are described. Several aromatic carbocations have been generated in supercritical ethane and fluoroform and representative spectral and kinetic data are presented. © 1995 American Institute of Physics.
引用
收藏
页码：3555 / 3559
页数：5
相关论文
共 50 条
  • [31] THE METHOXATIN SEMIQUINONE - A PULSE-RADIOLYSIS STUDY
    FARAGGI, M
    CHANDRASEKAR, R
    MCWHIRTER, RB
    KLAPPER, MH
    BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1986, 139 (03) : 955 - 960
  • [32] PULSE-RADIOLYSIS IN STUDY OF OXYGEN RADICALS
    SIMIC, MG
    METHODS IN ENZYMOLOGY, 1990, 186 : 89 - 100
  • [33] ELECTRON-TRANSFER REACTIONS STUDIED BY PULSE-RADIOLYSIS
    WILLSON, RL
    BIOCHEMICAL SOCIETY TRANSACTIONS, 1974, 2 (05) : 1082 - 1084
  • [34] AC CONDUCTIVITY CELL FOR PULSE-RADIOLYSIS OF LIQUIDS
    PARK, J
    VOELKER, WH
    GREGG, EC
    RADIATION RESEARCH, 1974, 59 (01) : 233 - 233
  • [35] FREE-RADICAL INDUCED REDOX REACTIONS OF DRUGS - A PULSE-RADIOLYSIS STUDY
    GYORGY, I
    FOLDIAK, G
    MAGYAR KEMIAI FOLYOIRAT, 1992, 98 (09): : 361 - 366
  • [36] REDOX REACTIONS OF DOPAMINE TRANSIENTS IN AQUEOUS-SOLUTION - A PULSE-RADIOLYSIS STUDY
    MAITY, DK
    MOHAN, H
    MITTAL, JP
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (04): : 919 - 923
  • [37] ONE-ELECTRON REDUCTION REACTIONS WITH ENZYMES IN SOLUTION - PULSE-RADIOLYSIS STUDY
    BISBY, RH
    CUNDALL, RB
    REDPATH, JL
    ADAMS, GE
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 : 51 - 63
  • [38] PULSE-RADIOLYSIS STUDY OF OH RADICAL REACTIONS IN SODIUM TETRAPHENYL BORATE SOLUTIONS
    BHAVE, RN
    CRAWFORD, CL
    HANRAHAN, RJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 198 : 17 - NUCL
  • [39] MICELLAR CATALYZED REDOX REACTIONS OF BILIRUBIN IN CTAB MEDIUM - A PULSE-RADIOLYSIS STUDY
    ADHIKARI, SK
    GUHA, SN
    GOPINATHAN, C
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1994, 26 (09) : 903 - 912
  • [40] PULSE-RADIOLYSIS STUDY OF XANTHINE AND HYPOXANTHINE OXIDATION
    PASQUIER, C
    SANTAMARIA, D
    FERRADINI, C
    PUCHEAULT, J
    JOURNAL OF CLINICAL CHEMISTRY AND CLINICAL BIOCHEMISTRY, 1982, 20 (06): : 404 - 404
12345