STRUCTURE OF 1-BENZHYDRYL-4-(2-BENZOYLETHYL)PIPERAZINIUM TETRACHLOROCUPRATE(II) HYDRATE

被引:3
|
作者
MACICEK, J [1 ]
TCHOLAKOVA, J [1 ]
PARVANOVA, M [1 ]
机构
[1] SOFIA TECHNOL UNIV, BU-1156 SOFIA, BULGARIA
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1993年 / 49卷
关键词
D O I
10.1107/S0108270192012058
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure consists of bulky Ph2CH(C4H10N2)CH2-CH2(CO)Ph2+ cations extended along the c axis, isolated [CuCl4]2- anions and a disordered water molecule scattered in a channel running parallel to the a axis through the centre of the unit cell. Both the tertiary-amine-group H atoms participate in hydrogen bonding with the water molecule and with two Cl atoms. A peculiarity of this structure is the presence of a short intermolecular O...C contact of 3.036(6) angstrom.
引用
收藏
页码:788 / 790
页数:3
相关论文
共 50 条
  • [41] Synthesis, Structure, Geometrical, and Spectral Characteristics of the (HLn)2[CuCl4] Complexes. Crystal and Molecular Structure of Bis(2-methylimidazolium) Tetrachlorocuprate(II)
    Kovalchukova, O. V.
    Palkina, K. K.
    Strashnova, S. B.
    Zaitsev, B. E.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (11) : 830 - 835
  • [43] 2-(1H-1,2,3-benzotriazol-1-ylmethyl)-1-benzoylethyl 4-chlorobenzoate
    Wan, J
    Peng, ZZ
    Li, XM
    Zhang, SS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O634 - O636
  • [44] The color and constitution of diazonium salts Part II Diazo-derivatives of as-benzoylethyl-1 4-naphthylenedtamine
    Morgan, GT
    Couzens, EG
    JOURNAL OF THE CHEMICAL SOCIETY, 1910, 97 : 1691 - 1697
  • [45] 2-(1H-1,2,3-Benzotriazol-1-ylmethyl)-1-benzoylethyl 4-ethylbenzoate
    Wan, J
    Peng, ZZ
    Li, XM
    Zhang, SS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O4218 - O4219
  • [46] 2-(1H-1,2,3-Benzotriazol-1-yl)-1-benzoylethyl 4-methylbenzoate
    Wu-Lan Zeng
    Yun-Chen Zhang
    Ming Hong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O3715 - U2183
  • [47] Clathrate hydrate formed with methane and 2-Propanol: Confirmation of structure II hydrate formation
    Ohmura, R
    Takeya, S
    Uchida, T
    Ebinuma, T
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (16) : 4964 - 4966
  • [48] STRUCTURE AND MAGNETIC-PROPERTIES OF BIS[(2,6-DIACETYLPYRIDINE DIOXIME)CHLOROCOPPER(II)] TETRACHLOROCUPRATE
    VASILEVSKY, IV
    STENKAMP, RE
    LINGAFELTER, EC
    SCHOMAKER, V
    WILLETT, RD
    ROSE, NJ
    INORGANIC CHEMISTRY, 1989, 28 (13) : 2619 - 2623
  • [49] Crystal structure of platinum(II) chloro(1,1,1-trifluoro-4-imino-2-pentanononate(hydrate)) [PtCl(ktf)H2O]
    Baidina, IA
    Zharkova, GI
    Gromilov, SA
    JOURNAL OF STRUCTURAL CHEMISTRY, 1998, 39 (04) : 549 - 553
  • [50] STRUCTURE OF BIS(TETRAETHYLAMMONIUM) TETRACHLOROCUPRATE(II) HEMIHYDRATE, [(C2H5)4N]2[CUCL4].0,5H2O
    MAHOUI, A
    LAPASSET, J
    MORET, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 358 - 362