STRUCTURE OF 1-BENZHYDRYL-4-(2-BENZOYLETHYL)PIPERAZINIUM TETRACHLOROCUPRATE(II) HYDRATE

被引：3
|
作者：
MACICEK, J [1 ]
TCHOLAKOVA, J [1 ]
PARVANOVA, M [1 ]
机构：
[1] SOFIA TECHNOL UNIV, BU-1156 SOFIA, BULGARIA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270192012058
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure consists of bulky Ph2CH(C4H10N2)CH2-CH2(CO)Ph2+ cations extended along the c axis, isolated [CuCl4]2- anions and a disordered water molecule scattered in a channel running parallel to the a axis through the centre of the unit cell. Both the tertiary-amine-group H atoms participate in hydrogen bonding with the water molecule and with two Cl atoms. A peculiarity of this structure is the presence of a short intermolecular O...C contact of 3.036(6) angstrom.
引用
收藏
页码：788 / 790
页数：3
相关论文
共 50 条
  • [1] 4-(2-Benzoylethyl) benzoic acid
    Lalancette, Roger A.
    Thompson, Hugh W.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1399 - U1427
  • [2] Thermochromism and structure of piperazinium tetrachlorocuprate(II) complexes
    Riley, MJ
    Neill, D
    Bernhardt, PV
    Byriel, KA
    Kennard, CHL
    INORGANIC CHEMISTRY, 1998, 37 (14) : 3635 - 3639
  • [3] 1-benzhydryl-4-(4-chlorophenylsulfonyl)piperazine
    Girisha, H. R.
    Naveen, S.
    Vinaya, K.
    Sridhar, M. A.
    Prasad, J. Shashidhara
    Rangappa, K. S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O358 - U1597
  • [4] RECYCLIZATION OF 1-METHYL-2-(2-BENZOYLETHYL)PYRIDINIUM IODIDE
    TERENIN, VI
    RUMYANTSEV, AN
    NOSYREV, PV
    YUDIN, LG
    GROMOV, SP
    BUNDEL, YG
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1988, (06): : 855 - 855
  • [5] Crystal and Molecular Structure Studies of a Novel 1-Benzhydryl-piperazine Derivative: 1-Benzhydryl-4-(4-chloro-2-fluoro-benzene-sulfonyl)-piperazine
    Naveen, S.
    Kumar, C. S. Ananda
    Manjunath, H. R.
    Vinaya, K.
    Prasad, S. B. Benaka
    Sridhar, M. A.
    Rangappa, K. S.
    Prasad, J. Shashidhara
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2009, 503 : 151 - 158
  • [6] Bis(1-methylguanidinium) tetrachloro-cuprate(II) and 4-(2-pyrimidin-1-io)piperazinium tetrachlorocuprate(II)
    Corzo-Suárez, R
    Díaz, I
    García-Granda, S
    Fernández, V
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : E385 - E387
  • [7] Synthesis, characterization, crystal and molecular structure analysis of a novel 1-benzhydryl piperazine derivative: 1-benzhydryl-4-(2-nitro-benzenesulfonyl)-piperazine
    K. Vinaya
    S. Naveen
    C. S. Ananda Kumar
    S. B. Benakaprasad
    M. A. Sridhar
    J. Shashidhara Prasad
    K. S. Rangappa
    Structural Chemistry, 2008, 19 : 765 - 770
  • [8] Synthesis, characterization, crystal and molecular structure analysis of a novel 1-benzhydryl piperazine derivative: 1-benzhydryl-4-(2-nitro-benzenesulfonyl)-piperazine
    Vinaya, K.
    Naveen, S.
    Kumar, C. S. Ananda
    Benakaprasad, S. B.
    Sridhar, M. A.
    Prasad, J. Shashidhara
    Rangappa, K. S.
    STRUCTURAL CHEMISTRY, 2008, 19 (05) : 765 - 770
  • [9] STRUCTURE OF THERMOCHROMIC CRYSTALS OF BENZIMIDAZOLIUM TETRACHLOROCUPRATE(II) HYDRATE
    BUKOWSKASTRZYZEWSKA, M
    SKOWERANDA, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2290 - 2293
  • [10] Structural Conformation of a Novel 1-Benzhydrylpiperazine Derivative: 1-Benzhydryl-4-(toluene-4-sulfonyl)-piperazine
    S. Naveen
    C. S. Ananda Kumar
    S. B. Benaka Prasad
    K. Vinaya
    M. A. Sridhar
    J. Shashidhara Prasad
    K. S. Rangappa
    Journal of Chemical Crystallography, 2009, 39 : 395 - 398
12345