THE OXIDATION-STATE OF GA IN GA/ZSM-5 LIGHT PARAFFIN AROMATIZATION CATALYSTS

被引:47
|
作者
PRICE, GL [1 ]
KANAZIREV, V [1 ]
机构
[1] BULGARIAN ACAD SCI,INST ORGAN CHEM,BU-1040 SOFIA,BULGARIA
来源
JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 66卷 / 01期
关键词
D O I
10.1016/0304-5102(91)85026-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gallium nitrate-impregnated NaZSM-5 and HZSM-5 light paraffin aromatization catalysts have been reduced via hydrogen in a microbalance, and a disparity in the degree of reduction of gallium was determined. This result suggests that catalytic activity differences in the two materials may be associated with the degree of gallium reduction.
引用
收藏
页码:115 / 120
页数:6
相关论文
共 50 条
  • [21] The Role Played by Ga-Pt Nanoparticles in the Aromatization of Lower Alkanes on ZSM-5 Zeolites
    M. N. Mikhailov
    A. A. Dergachev
    I. V. Mishin
    L. M. Kustov
    A. L. Lapidus
    Russian Journal of Physical Chemistry A, Focus on Chemistry, 2008, 82 (4): : 612 - 618
  • [22] The role played by Ga-Pt nanoparticles in the aromatization of lower alkanes on ZSM-5 zeolites
    Mikhailov, M. N.
    Dergachev, A. A.
    Mishin, I. V.
    Kustov, L. M.
    Lapidus, A. L.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (04) : 612 - 618
  • [23] Aromatization of light alkanes over ZSM-5 catalysts Influence of the particle properties of the zeolite
    Smiesková, A
    Rojasová, E
    Hudec, P
    Sabo, L
    APPLIED CATALYSIS A-GENERAL, 2004, 268 (1-2) : 235 - 240
  • [24] STUDIES ON THE COKE FORMATION ON GALLIUM MODIFIED ZSM-5 CATALYSTS FOR AROMATIZATION OF LIGHT ALKANES
    CHENG, C
    TAN, C
    ZHUO, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 13 - PETR
  • [25] DRIFTS study of the nature and chemical reactivity of gallium ions in Ga/ZSM-5 II. Oxidation of reduced Ga species in ZSM-5 by nitrous oxide or water
    Kazansky, VB
    Subbotina, IR
    van Santen, RA
    Hensen, EJM
    JOURNAL OF CATALYSIS, 2005, 233 (02) : 351 - 358
  • [26] A new way to obtain acid or bifunctional catalysts V. Considerations on bifunctionality of the propane aromatization reaction over [Ga,Al]-ZSM-5 catalysts
    Montes, A
    Giannetto, G
    APPLIED CATALYSIS A-GENERAL, 2000, 197 (01) : 31 - 39
  • [27] PREPARATION OF BIFUNCTIONAL CATALYSTS BY DEGALLIFICATION OF NH4-(GA)-ZSM-5 ZEOLITES
    GIANNETTO, G
    MONTES, A
    GNEP, NS
    GUISNET, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 110 - PETR
  • [28] Cracking and aromatization properties of some metal modified ZSM-5 catalysts for light alkane conversions
    Viswanadham, N
    Muralidhar, G
    Rao, TSRP
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 223 (1-2) : 269 - 274
  • [29] KINETIC-STUDY OF N-BUTANE AROMATIZATION ON ZSM-5 AND GALLIUM BEARING ZSM-5 CATALYSTS
    LEVANMAO, R
    YAO, JH
    APPLIED CATALYSIS, 1991, 79 (01): : 77 - 87
  • [30] DETERMINATION OF FRAMEWORK CONCENTRATIONS OF GALLIUM IN [GA]-ZSM-5
    KOFKE, TJG
    GORTE, RJ
    KOKOTAILO, GT
    APPLIED CATALYSIS, 1989, 54 (02): : 177 - 188