TRINUCLEAR COMPLEXATION OF 2,6-BIS(ACETYLACETOXYMETHYL)PYRIDINE WITH PD(II) AND CU(II) IONS

被引：12
|
作者：
KAWATO, T
KOYAMA, H
KANATOMI, H
MURAMOTO, Y
机构：
[1] Laboratory of Chemistry, College of General Education, Kyushu University, Chuo-ku, Fukuoka, 810, Ropponmatsu
来源：
INORGANICA CHIMICA ACTA | 1991年 / 183卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)83001-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [PdCl2(PhCN)2] with 2,6-disubstituted pyridines (L) gave a new series of trans-[PdCl2L2] complexes. beta-Ketoester substituents in the ligands were found to form O-O chelate compounds with a Cu(II)ion. The Pd(II) complex of 2,6-bis(acetylacetoxymethyl)pyridine reacted with copper(II) acetate in dioxane to yield a (Cu(II), Pd(II), Cu(II)) trinuclear complex, which incorporated dioxane in the crystals. NMR, IR and reflectance spectra of the products were examined.
引用
收藏
页码：107 / 112
页数：6
相关论文
共 50 条
  • [31] COPPER(II) AND ZINC(II) COORDINATION-COMPOUNDS OF TRIDENTATE BIS(BENZIMIDAZOLE)PYRIDINE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF BIS[2,6-BIS(1'-METHYLBENZIMIDAZOL-2'-YL)PYRIDINE]COPPER(II) DIPERCHLORATE MONOHYDRATE AND (ACETONITRILE)[2,6-BIS(BENZIMIDAZOL-2'-YL)PYRIDINE](PERCHLORATO)COPPER(II) PERCHLORATE,
    SANNI, SB
    BEHM, HJ
    BEURSKENS, PT
    VANALBADA, GA
    REEDIJK, J
    LENSTRA, ATH
    ADDISON, AW
    PALANIANDAVAR, M
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (06): : 1429 - 1435
  • [32] Complexation of copper(II) with 2,6-bis(dimethylaminomethyl)-4-methylphenol in the presence of surfactants
    Sal'nikov, Yu. I.
    Boos, G. A.
    Ryzhkina, I. S.
    Lukashenko, S. S.
    Mingaleeva, G. R.
    COLLOID JOURNAL, 2007, 69 (05) : 632 - 638
  • [33] Complexation of copper(II) with 2,6-bis(dimethylaminomethyl)-4-methylphenol in the presence of surfactants
    Yu. I. Sal’nikov
    G. A. Boos
    I. S. Ryzhkina
    S. S. Lukashenko
    G. R. Mingaleeva
    Colloid Journal, 2007, 69 : 632 - 638
  • [34] 2,6-bis(2-benzimidazolyl)pyridine as a chemosensor for fluoride ions
    Chetia, Bolin
    Iyer, Parameswar K.
    TETRAHEDRON LETTERS, 2008, 49 (01) : 94 - 97
  • [35] {2,6-Bis[1-(phenylimino)ethyl]pyridine}dichloridomanganese(II) dichloromethane hemisolvate
    Guo, Meng-Ping
    Guo, Gui-Quan
    Guo, Hui-Rui
    Zhong, Di-Chang
    Zhou, Wei-Qiang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M3025 - U1496
  • [36] Synthesis, characterization, and butadiene polymerization of iron(III), iron(II) and cobalt(II) chlorides bearing 2,6-bis(2-benzimidazolyl)pyridyl or 2,6-bis(pyrazol)pyridine ligand
    Gong, Dirong
    Jia, Xiaoyu
    Wang, Baolin
    Zhang, Xuequan
    Jiang, Liansheng
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 702 : 10 - 18
  • [37] Studies on the Atropisomerism of Fe(II) 2,6-Bis(N-arylimino)pyridine Complexes
    Campora, Juan
    Angeles Cartes, M.
    Rodriguez-Delgado, Antonio
    Marcos Naz, A.
    Palma, Pilar
    Perez, Carmen M.
    INORGANIC CHEMISTRY, 2009, 48 (08) : 3679 - 3691
  • [38] {2,6-Bis[bis(2-pyridylmethyl)aminomethyl]-pyridine}cobalt(II) bis( perchlorate) 0.365-hydrate
    Hazell, Alan
    Toftlund, Hans
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M326 - M327
  • [39] {2,6-Bis[bis(2-pyridylmethyl)aminomethyl]pyridine}-manganese(II) bis(perchlorate) 0.435-hydrate
    Hazell, Alan
    Toftlund, Hans
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M328 - M329
  • [40] BINDING ABILITY OF 2,6-BIS(METHYLTHIOMETHYL)PYRIDINE WITH PROTON, PALLADIUM(II) AND COPPER(II) IN AQUEOUS-SOLUTIONS
    CANOVESE, L
    CHESSA, G
    MARANGONI, G
    PITTERI, B
    UGUAGLIATI, P
    VISENTIN, F
    INORGANICA CHIMICA ACTA, 1991, 186 (01) : 79 - 86
12345