TRINUCLEAR COMPLEXATION OF 2,6-BIS(ACETYLACETOXYMETHYL)PYRIDINE WITH PD(II) AND CU(II) IONS

被引：12
|
作者：
KAWATO, T
KOYAMA, H
KANATOMI, H
MURAMOTO, Y
机构：
[1] Laboratory of Chemistry, College of General Education, Kyushu University, Chuo-ku, Fukuoka, 810, Ropponmatsu
来源：
INORGANICA CHIMICA ACTA | 1991年 / 183卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)83001-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [PdCl2(PhCN)2] with 2,6-disubstituted pyridines (L) gave a new series of trans-[PdCl2L2] complexes. beta-Ketoester substituents in the ligands were found to form O-O chelate compounds with a Cu(II)ion. The Pd(II) complex of 2,6-bis(acetylacetoxymethyl)pyridine reacted with copper(II) acetate in dioxane to yield a (Cu(II), Pd(II), Cu(II)) trinuclear complex, which incorporated dioxane in the crystals. NMR, IR and reflectance spectra of the products were examined.
引用
收藏
页码：107 / 112
页数：6
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