SHOCK-TUBE AND MODELING STUDY OF PROPENE PYROLYSIS

被引：68

作者：

HIDAKA, Y ^{[1
]}

NAKAMURA, T ^{[1
]}

TANAKA, H ^{[1
]}

JINNO, A ^{[1
]}

KAWANO, H ^{[1
]}

HIGASHIHARA, T ^{[1
]}

机构：

[1] MATSUE COLL TECHNOL,MATSUE 690,JAPAN

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1992年 / 24卷 / 09期

关键词：

D O I：

10.1002/kin.550240902

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thermal decomposition of propene behind reflected shock waves with 1200 < T5 < 1800 K and 1.6 x 10(-5) < rho-5 < 2.7 x 10(-5) mol/cm3 was studied by IR laser kinetic absorption spectroscopy and gas-chromatographic analysis of reaction products. The present data together with earlier shock tube data were satisfactorily modeled with a 51-reaction mechanism. As the initial step of the reaction, three channels, C3H6 = CH3 + C2H3 (1), C3H6 = H + AC3H5 (2), and C3H6 = CH4 + C2H2 (3), were necessary to interpret all the experimental data.

引用

页码：761 / 780

页数：20

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