SHOCK-TUBE AND MODELING STUDY OF PROPENE PYROLYSIS

被引：68
|
作者：
HIDAKA, Y [1 ]
NAKAMURA, T [1 ]
TANAKA, H [1 ]
JINNO, A [1 ]
KAWANO, H [1 ]
HIGASHIHARA, T [1 ]
机构：
[1] MATSUE COLL TECHNOL,MATSUE 690,JAPAN
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1992年 / 24卷 / 09期
关键词：
D O I：
10.1002/kin.550240902
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The thermal decomposition of propene behind reflected shock waves with 1200 < T5 < 1800 K and 1.6 x 10(-5) < rho-5 < 2.7 x 10(-5) mol/cm3 was studied by IR laser kinetic absorption spectroscopy and gas-chromatographic analysis of reaction products. The present data together with earlier shock tube data were satisfactorily modeled with a 51-reaction mechanism. As the initial step of the reaction, three channels, C3H6 = CH3 + C2H3 (1), C3H6 = H + AC3H5 (2), and C3H6 = CH4 + C2H2 (3), were necessary to interpret all the experimental data.
引用
收藏
页码：761 / 780
页数：20
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