STEREOSELECTIVE ADDITION OF SULFUR-STABILIZED CARBANIONS

被引：0
|
作者：
BRUNCK, JS
VOSS, J
机构：
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 95-6卷 / 1-4期
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of dithioacetal sulfoxides 2 with different electrophiles was investigated. Sulfoxides 2 were easily deprotonated by different bases and reacted with variuos electrophiles. The carbanion of 2 exhibits configurational stability. Asymmetric induction was observed upon the reaction with prochiral electrophiles. Generation of the carbonyl functionality can easily be performed.
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页码：403 / 404
页数：2
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