STEREOSELECTIVE ADDITION OF SULFUR-STABILIZED CARBANIONS

被引：0

作者：

BRUNCK, JS

VOSS, J

机构：

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 95-6卷 / 1-4期

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D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dithioacetal sulfoxides 2 with different electrophiles was investigated. Sulfoxides 2 were easily deprotonated by different bases and reacted with variuos electrophiles. The carbanion of 2 exhibits configurational stability. Asymmetric induction was observed upon the reaction with prochiral electrophiles. Generation of the carbonyl functionality can easily be performed.

引用

页码：403 / 404

页数：2

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