PREPARATION AND PH DEPENDENT REVERSIBLE COLOR-CHANGE OF (HEXAFLUOROACETYLACETONATO)BIS(ETHYLENEDIAMINE)CHROMIUM(III) COMPLEX

被引：2

作者：

KATOU, T ^{[1
]}

YAMAMOTO, Y ^{[1
]}

KURODA, K ^{[1
]}

WATANABE, K ^{[1
]}

KITAMURA, Y ^{[1
]}

机构：

[1] EHIME UNIV,FAC SCI,DEPT CHEM,MATSUYAMA,EHIME 790,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1991年 / 180卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)83058-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex ion was newly prepared as a hexafluorophosphate perchlorate salt. The aqueous solution of this complex shows a pH dependent, rapid and reversible color change. This phenomenon is analogous to that observed for its Co(III) analog and may be explained by a hydroxide ion addition equilibrium to the coordinating hexafluoroacetylacetonato ligand. The estimated equilibrium constant is significantly larger than that for its Co(III) analog.

引用

页码：13 / 14

页数：2