CRYSTAL-STRUCTURE OF DECACALCIUM TETRAPOTASSIUM HEXAKIS(PYROPHOSPHATE) NONAHYDRATE

被引：1
|
作者：
MATHEW, M [1 ]
AMMON, HL [1 ]
机构：
[1] UNIV MARYLAND,DEPT CHEM & BIOCHEM,COLLEGE PK,MD 20742
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1995年 / 25卷 / 05期
关键词：
CALCIUM PHOSPHATE; CALCIUM PYROPHOSPHATE; CALCIUM POTASSIUM PYROPHOSPHATE; CRYSTAL STRUCTURE; LAYER-TYPE STRUCTURE;
D O I：
10.1007/BF01665172
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of Ca10K4(P2O7)(6) . 9H(2)O has been determined by single crystal X-ray diffraction. Crystals are hexagonal, space group P6(3)cm with a = 11.761(1), c = 9.770(1) Angstrom, and Z = 1. The structure was refined to R = 0.028 and R(w) = 0.037 for 468 reflections with I greater than or equal to 3 sigma(I). The structure consists of a compact assembly of Ca and P2O7 ions arranged in layers perpendicular to the c-axis in a hexagonal array with relatively large open channels along the c-axis. The K ions and the water molecules are located in these open channels and are disordered.
引用
收藏
页码：219 / 222
页数：4
相关论文
共 50 条
  • [21] CRYSTAL STRUCTURE OF TETRAPOTASSIUM DIHYDROGENDECAOXODIIODATE(7) OCTAHYDRATE
    FERRARI, A
    BRAIBANT.A
    TIRIPICC.A
    ACTA CRYSTALLOGRAPHICA, 1965, 19 : 629 - &
  • [22] CRYSTAL-STRUCTURE OF HEXAKIS(1,8-NAPHTHYRIDINE)PRASEODYMIUM(III) PERCHLORATE
    CLEARFIELD, A
    GOPAL, R
    OLSEN, RW
    INORGANIC CHEMISTRY, 1977, 16 (04) : 911 - 915
  • [23] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HEXAKIS(THIOCYANATO-N)-COBALTATE(II) ANION
    MALI, TN
    HANCOCK, RD
    BOEYENS, JCA
    OOSTHUIZEN, EL
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (04): : 1161 - 1163
  • [24] CRYSTAL-STRUCTURE OF HEXAKIS(PYRIDINE 1-OXIDE)MERCURY(II) BISPERCHLORATE
    KEPERT, DL
    TAYLOR, D
    WHITE, AH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (06): : 670 - 673
  • [25] Crystal structure of iron(III) perchlorate nonahydrate
    Hennings, Erik
    Schmidt, Horst
    Voigt, Wolfgang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 477 - +
  • [26] CRYSTAL-STRUCTURE OF AQUA-HEXAKIS-(1,3-DIMETHYLUREA)ERBIUM(III)
    MATTOS, MC
    SURCOUF, E
    MORNON, JP
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (JUN15): : 1855 - 1861
  • [27] CRYSTAL-STRUCTURE OF TETRAPOTASSIUM DECASELENIDO-TETRAGERMANATE, K4[GE4SE10]
    EISENMANN, B
    HANSA, J
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1993, 206 : 101 - 102
  • [28] STRUCTURE OF CYCLODEXTRIN COMPLEX .4. CRYSTAL-STRUCTURE OF ALPHA-CYCLODEXTRIN-SODIUM 1-PROPANESULFONATE NONAHYDRATE
    HARATA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1977, 50 (05) : 1259 - 1266
  • [29] CRYSTAL-STRUCTURE OF ALUMINUM SODIUM PYROPHOSPHATE, NAALP2O7
    ALKEMPER, J
    PAULUS, H
    FUESS, H
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1994, 209 (07): : 616 - 616
  • [30] CRYSTAL-STRUCTURE OF COPPER(II) CIMETIDINE SULFATE NONAHYDRATE - CATION DISTORTION AND STRUCTURE ISOMERISM IN 3 COPPER(II) CIMETIDINE COMPLEXES
    SOTO, L
    LEGROS, JP
    SANCHO, A
    POLYHEDRON, 1988, 7 (04) : 307 - 314
12345