Crystal Structure of a Mononuclear Iron(III) Complex, Dichloridobis(1,10-phenanthroline-kappa N-2, N ') iron(III) Hexafluoridophosphate-acetonitrile

被引：1
|
作者：
Kaneko, Satoshi [1 ]
Mitsuhashi, Ryoji [2 ]
Mikuriya, Masahiro [2 ]
Sakiyama, Hiroshi [1 ]
机构：
[1] Yamagata Univ, Fac Sci, Dept Sci, 1-4-12 Kojirakawa, Yamagata 9908560, Japan
[2] Kwansei Gakuin Univ, Sch Sci & Technol, Dept Appl Chem Environm, 2-1 Gakuen, Sanda 6691337, Japan
来源：
X-RAY STRUCTURE ANALYSIS ONLINE | 2018年 / 34卷
关键词：
D O I：
10.2116/xraystruct.34.49
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A mononuclear iron(III) complex, [FeCl2(phen)(2)][PF6]center dot MeCN [dichloridobis(1,10-phenanthroline-kappa N-2, N') iron(III) hexafluoridophosphate-acetonitrile], was synthesized, and characterized by single-crystal X-ray method. The compound crystallized in the monoclinic space group C2/c and Z = 4 with cell parameters a = 16.3586(12) angstrom, b = 12.6022(9) angstrom, c = 13.0231(9)angstrom, beta = 103.6760(10)degrees, V = 2608.7(3)angstrom(3). The R-1 [I > 2 sigma(I)] and wR(2) (all data) values were 0.0345 and 0.0949, respectively, for all 3161 independent reflections. Analysis revealed that the complex cation has an octahedral coordination geometry with a Cl2N4 donor set with two chloride ligands at the cis-positions.
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页码：49 / 50
页数：2
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