Tris(5,6-dimethyl-1,10-phenanthroline-kappa N-2,N ')iron(II) bis(tricyanomethanide)

被引：4

作者：

Vahovska, Lucia ^{[1
]}

Potocnak, Ivan ^{[1
]}

机构：

[1] Safarik Univ, Fac Sci, Inst Chem, Moyzesova 11, SK-04154 Kosice, Slovakia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812046880

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Fe(C14H12N2)(3)](C4N3)(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the FeII atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe-N distance of 1.963 (4) angstrom giving a distorted octahedral geometry. The crystal structure is stabilized by weak C-H center dot center dot center dot N hydrogen bonds and C N center dot center dot center dot pi-interactions between planar [maximum deviations of 0.024 (3) and 0.015 (3) angstrom] tcm anions and pyridine rings of dimephen [N2 center dot center dot center dot centroid = 3.531 (3) and 3.726 (3) angstrom; C N center dot center dot center dot centroid = 96.4 (2) and 97.1 (2)degrees].

引用

页码：M1524 / +

页数：13

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