CONSTRUCTION OF HIGHLY EFFICIENT MN-SALEN CATALYST FOR ASYMMETRIC EPOXIDATION OF CONJUGATED CIS-OLEFINS

被引：0
|
作者：
SASAKI, H [1 ]
IRIE, R [1 ]
KATSUKI, T [1 ]
机构：
[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN
来源：
SYNLETT | 1994年 / 05期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
On the basis of the newly proposed hypothesis on the olefin's approach to metal-oxo species, highly efficient (salen)manganese(III) complex (3) was synthesized as a catalyst for asymmetric epoxidation. With this catalyst, the highest level of enantioselectivity was realized in the epoxidation of conjugated cis-olefins.
引用
收藏
页码：356 / 358
页数：3
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