RESONANCE-ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY OF DIMETHYL SULFIDE

被引：22
|
作者：
MORGAN, RA [1 ]
ORREWING, AJ [1 ]
ASHFOLD, MNR [1 ]
BUMA, WJ [1 ]
WALES, NPL [1 ]
DELANGE, CA [1 ]
机构：
[1] UNIV AMSTERDAM,PHYS CHEM LAB,1018 WS AMSTERDAM,NETHERLANDS
来源：
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 19期
关键词：
D O I：
10.1039/ft9959103339
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report the first multiphoton study of the electronic spectrum of the dimethyl sulfide molecule. The interpretation we present is based on analysis of the two- and three-photon resonance enhanced multiphoton ionisation (REMPI) spectra and measurements of the kinetic energies of the photoelectrons resulting from the REMPI process. Members of four (possibly five) Rydberg series are identified and a refined value of the first ionisation limit of dimethyl sulfide is obtained: E(i) = 8.710+/-0.005 eV (70250+/-40 cm(-1)). As in our previous study of the related divalent sulfide methanethiol, we detect the presence of slower electrons in the photoelectron spectra which can be interpreted in terms of near resonant inter-Rydberg state vibronic mixing.
引用
收藏
页码：3339 / 3346
页数：8
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