DC CONDUCTIVITY OF SOL-GEL DERIVED GLASSES IN THE SYSTEM FE2O3-SIO2

被引:0
|
作者
BRAHMA, P [1 ]
CHAKRAVORTY, D [1 ]
MITRA, S [1 ]
机构
[1] GURUDAS COLL,CALCUTTA 700054,INDIA
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Glasses in the series x Fe2 O3.(1-x) SiO2 with 0.01 < x < 0.1 have been prepared by sol-gel technique. DC resistivity of these glasses have been investigated over the temperature range 300 to 600K. The temperature variation of resistivity is explained on the basis of a small polaron hopping conduction mechanism, the Fe2+ and Fe3+ ions acting as the hopping sites. The high temperature data have been analysed by both the T-1/4 and T-2/5 law respectively as formulated by Triberis and Friedman. The density of localised states is calculated to be in the range 10(19)-10(20) eV-1 Cm-3.
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页码:1139 / 1150
页数:12
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