REARRANGEMENT IN THE NITROGEN SERIES .2. SIGMATROPIC [2,3]-WITTIG REARRANGEMENT OF ALPHA-ALLYLIC-HETEROSUBSTITUTED METHYLPHOSPHONATES .3. HIGH DIASTEREOSELECTIVITY IN THE REARRANGEMENT OF ANION OF DIMENTHYL ALLYLOXYMETHYLPHOSPHONATE

被引：0

作者：

GULEAPURCARESCU, M ^{[1
]}

ABOUTJAUDET, E ^{[1
]}

COLLIGNON, N ^{[1
]}

机构：

[1] INSA,IRCOF,HETEROCHIM ORGAN LAB,F-76131 MONT ST AIGNAN,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 37期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A diastereoselectivity up to 90% was achieved in the title rearrangement of lithiated allyloxymethylphosphonates, by using the cheaply available chiral dimenthylphosphonyl ester group as stereo-directing auxiliary. The absolute configuration of the newly formed chiral center was assigned by usual chemical conversions.

引用

页码：6635 / 6638

页数：4

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