KINETIC-ANALYSIS AND MODELING OF THE ESTERIFICATION OF OLEIC-ACID AND OLEYL ALCOHOL USING COBALT CHLORIDE AS CATALYST

被引:18
|
作者
SANCHEZ, N [1 ]
COTERON, A [1 ]
MARTINEZ, M [1 ]
ARACIL, J [1 ]
机构
[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT INGN QUIM,CIUDAD UNIV,E-28040 MADRID,SPAIN
关键词
D O I
10.1021/ie00008a021
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The kinetic of the homogeneous liquid phase synthesis of an analog of jojoba oil in a stirred tank reactor using cobalt chloride as catalyst has been studied at different temperatures, concentrations of the catalyst, and acid/alcohol molar ratios. A mathematical model that Predicts quite well the experimental results has been developed.
引用
收藏
页码:1985 / 1988
页数:4
相关论文
共 50 条
  • [11] Process optimization and kinetic modeling for esterification of propionic acid with benzyl alcohol on ion-exchange resin catalyst
    Chandane, Vishal Suresh
    Rathod, Ajit Pralhad
    Wasewar, Kailas Lachchhuram
    Sonawane, Shriram Shaligram
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2017, 34 (04) : 987 - 996
  • [12] Process optimization and kinetic modeling for esterification of propionic acid with benzyl alcohol on ion-exchange resin catalyst
    Vishal Suresh Chandane
    Ajit Pralhad Rathod
    Kailas Lachchhuram Wasewar
    Shriram Shaligram Sonawane
    [J]. Korean Journal of Chemical Engineering, 2017, 34 : 987 - 996
  • [13] Investigation of the kinetic parameters of tetrachloro[ethylenebis diphenylphosphine)]tungsten(IV) as a Lewis acid catalyst in the esterification of oleic acid
    Kingsley, Molly C.
    Hartmann, Richard W.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [14] Bentonite pillarization using sonication in a solid acid catalyst preparation for the oleic acid esterification reaction
    Rinaldi, Nino
    Purba, Nova Dwi Enjelina
    Kristiani, Anis
    Agustian, Egi
    Widjaya, Robert Ronal
    Dwiatmoko, Adid Adep
    [J]. CATALYSIS COMMUNICATIONS, 2023, 174
  • [15] ANALYSIS AND MODELING OF 1-BUTYL ALCOHOL ESTERIFICATION WITH HYDROBROMIC ACID AND SULFURIC-ACID AS HOMOGENEOUS CATALYST
    ORTIZ, I
    DECAMPOS, D
    IRABIEN, JA
    [J]. CHEMICAL ENGINEERING SCIENCE, 1987, 42 (10) : 2467 - 2471
  • [16] Synthesis of Biosurfactants: Enzymatic Esterification of Diglycerol and Oleic Acid. 1. Kinetic Modeling
    Martinez, Mercedes
    Oliveros, Ruben
    Aracil, Jose
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (11) : 6609 - 6614
  • [17] REGULATION OF PLATELET PROTEIN-KINASE-C BY OLEIC-ACID - KINETIC-ANALYSIS OF ALLOSTERIC REGULATION AND EFFECTS ON AUTOPHOSPHORYLATION, PHORBOL ESTER BINDING, AND SUSCEPTIBILITY TO INHIBITION
    ELTOUNY, S
    KHAN, W
    HANNUN, Y
    [J]. JOURNAL OF BIOLOGICAL CHEMISTRY, 1990, 265 (27) : 16437 - 16443
  • [18] Kinetic studies on esterification of acetic acid with isopropyl alcohol in presence of novel solid catalyst
    Mekala, Mallaiah
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2021, 19 (01) : 87 - 95
  • [19] Impregnation of 12-tungstophosphoric acid on tonsil: An effective catalyst for esterification of formic acid with n-butyl alcohol and kinetic modeling
    Altiokka, Mehmet R.
    Akbay, Elif
    Him, Zeynep
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 385 : 18 - 25
  • [20] An assessment on kinetic modeling of esterification reaction from oleic acid and methyl acetate over USY zeolite
    Ketzer, Felipe
    de Castilhos, Fernanda
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2021, 314