DIIMINOPHOSPHINATES OF LITHIUM, SAMARIUM AND YTTERBIUM - MOLECULAR-STRUCTURES LI[PH2P(NSIME3)2](THF)2 AND [PH2P(NSIME3)2]2SM(MU-I)2LI(THF)2

被引：68

作者：

RECKNAGEL, A ^{[1
]}

STEINER, A ^{[1
]}

NOLTEMEYER, M ^{[1
]}

BROOKER, S ^{[1
]}

STALKE, D ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86331-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular structure of Li[Ph2P(NSiMe3)2]THF)2 (2) has been determined by an X-ray diffraction study. A four-membered LiNPN ring forms the central unit of the monomeric molecule. YbI2 reacts with two equivalents of Li[Ph2P(NSiMe3)2] (1) to give the novel ytterbium(II)diiminophosphinate [Ph2P(NSiMe3)2]2Yb(THF)2 (3). A similar reaction of 1 with SmI2 affords the samarium(III) derivative [Ph2P(NSiMe3)2]2Sm(mu-1)2Li(THF)2 (4) whose structure has also been determined by an X-ray diffraction study.

引用

页码：327 / 335

页数：9

共 50 条

[31] Synthesis and Crystal Structure of （1,3-tBu2C5H3）2Sm（ μ-Cl）2Li（THF）2
CHENG Yan Xiang JIN Guo Xin ② JIA Heng Qing\ XING Yan LIN Yong Hua (Changchun Institute of Applied Chemistry
结构化学, 2001, (01) : 31 - 33
[32] Synthesis and crystal structure of (1,3-tBu2C5H3)2Sm(μ-Cl)2Li(THF)2
Cheng, YX
Jin, GX
Jia, HQ
Xing, Y
Lin, YH
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (01) : 31 - 33
[33] Synthesis and reactivity of samarium complexes with bis(diphenylchalcogenophosphoryl)amides. The structures of [{eta(2)-(Ph2PS)(2)N}(2)Sm(thf)(2)], [{eta(3)-(Ph2PSe)(2)N}{eta(2)-(Ph2PSe)(2)N}Sm(thf)(2)], [{eta(3)-(Ph2PSe)(2)N}(2)Sm(SePh)(thf)], and [{eta(3)-(Ph2PSe)(2)N}(2)Sm(SeMes)(thf)]
Geissinger, M
Magull, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (05): : 755 - 761
[34] Formation and structure of Li(THF)(2)[eta(2)-((t)Bu(2)P)(2)P], Li(TMEDA)[eta(2)-((t)Bu(2)P)(2)P], Li(THF)(2)[eta(2)-((Pr2P)-Pr-i)(2)P], Li(THF)(2)[eta(2)-(Et(2)N)(2)P-P-P(t)Bu(2)], Li(THF)(2)[eta(2)-((t)Bu(2)P-P-(PPr2)-Pr-i] and ((t)Bu(2)P)(2)P-SiMe(3)
Kovacs, I
Krautscheid, H
Matern, E
Sattler, E
Fritz, G
Honle, W
Borrmann, H
vonSchnering, HG
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (09): : 1564 - 1572
[35] The first biscarbene complex of a group 4 metal:: [Zr{C(Me2P=NSiMe3)2}2]
Aparna, K
Babu, RPK
McDonald, R
Cavell, RG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (23) : 4400 - +
[36] [CH(Me)P(Et)(2)NSiMe3](-) - A carbanion that functions as a bridging ligand
Muller, A
Neumuller, B
Dehnicke, K
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (21): : 2350 - 2352
[37] Syntheses and characterization of Ta(=NSiMe3)[N(SiMe3)2]X2 (X = CH2Ph, NMe2)
Hunter, Seth C.
Xue, Zi-Ling
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[38] Synthesis and Structure of [Li2C(PPh2=NSiMe3)(PPh2=S)]: A Geminal Dianionic Ligand
Chen, Jun-Hui
Guo, Jiayi
Li, Yongxin
So, Cheuk-Wai
ORGANOMETALLICS, 2009, 28 (15) : 4617 - 4620
[39] The preparation and structures of Ph2P(E)OH and Ph2P(E)OP(E)Ph-2 (E=S, Se)
Pilkington, MJ
Slawin, AMZ
Williams, DJ
Woollins, JD
MAIN GROUP CHEMISTRY, 1995, 1 (01) : 145 - 151
[40] COMPLEXES WITH PHOSPHINOMETHANE AND PHOSPHINOMETHANIDE LIGANDS .16. CO-LIGANDS AND SUBSTITUENT-DEPENDENCE OF THE COORDINATION OF DIPHOSPHINOMETHANIDE LIGANDS [(R2P)2CX]- TO LI+ AND CRYSTAL-STRUCTURES OF ((THF)LI[(PH2P)2CH])2, ((THF)LI[(ME2P)2C(SIME3)])2 AND ((TMEDA)LI[(ME2P)2C(SIME3)])
KARSCH, HH
DEUBELLY, B
MULLER, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 352 (1-2) : 47 - 59

← 1 2 3 4 5 →