CHLORO[(1-METHYL-2-IMIDAZOLYL-KAPPA-N-3-METHYL)BIS(2-PYRIDYL-KAPPA-N-METHYL)AMINE-KAPPA-N]COPPER(II) HEXAFLUOROPHOSPHATE, [CUCL(C17H19N5)]PF6

被引：4
|
作者：
WANG, JP
MASHUTA, MS
RICHARDSON, JF
BUCHANAN, RM
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S010827019400644X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The coordination polyhedron of the Cu-II ion in the title compound is best described as a distorted trigonal bipyramid with an imidazole and two pyridine N atoms bonded in the equatorial plane, and a Cl- ion and an amine N atom bonded along the axial direction. The Cu-N(amine) bond length is 2.087 (4) Angstrom, while the Cu-N(imidazole) and Cu-N(pyridine) bond lengths are 1.979 (3), 2.044 (3) and 2.153 (3) Angstrom, respectively. The Cu-Cl distance is 2.232(1) Angstrom. A fairly satisfactory model was found for the disordered PF6- counterion.
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页码：50 / 52
页数：3
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