CHARGE DISCHARGE CYCLING BEHAVIOR OF PITCH-BASED CARBON-FIBER IN ORGANIC ELECTROLYTE-SOLUTIONS

被引：71
|
作者：
MORITA, M
NISHIMURA, N
MATSUDA, Y
机构：
[1] Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Yamaguchi University, Ube, 755
来源：
ELECTROCHIMICA ACTA | 1993年 / 38卷 / 13期
关键词：
CARBON FIBER; LITHIUM BATTERY; RECHARGEABLE; LITHIUM INTERCALATION; AC IMPEDANCE;
D O I：
10.1016/0013-4686(93)85068-A
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Pitch-based carbon fiber in which a graphite structure is highly oriented in the radial direction from its central axis has been examined as a negative electrode matrix of a rechargeable lithium battery. The cyclic voltammograms for the fiber electrode showed that a reversible process of lithium intercalation/deintercalation occurred in propylene carbonate (PC)-based solutions containing various lithium salts. A high discharge capacity of about 220 Ah kg carbon-1 and a nearly 100% coulombic efficiency were observed in PC dissolving LiClO4 (1 mol dm-3) under constant-current charge/discharge cycling. The effects of the electrolyte salt on the cycling behavior of the carbon fiber electrode were investigated by means of an ac impedance technique. The battery performance of the carbon fiber was tested using model full cells with lithiated manganese oxide and vanadium oxide cathodes.
引用
收藏
页码：1721 / 1726
页数：6
相关论文
共 50 条
  • [21] High performance pitch-based carbon fiber
    Tadokoro, H
    Tsuji, N
    Shibata, H
    Furuyama, M
    Arai, Y
    Doken, Y
    Kobayashi, K
    Kato, O
    [J]. MATERIALS AND PROCESS CHALLENGES: AGING SYSTEMS, AFFORDABILITY, ALTERNATIVE APPLICATIONS, BOOKS 1 AND 2, 1996, 41 (BK 1-2): : 1134 - 1138
  • [22] THE CORRELATION OF THERMAL-CONDUCTIVITY WITH ELECTRICAL-RESISTIVITY IN MESOPHASE PITCH-BASED CARBON-FIBER
    LAVIN, JG
    BOYINGTON, DR
    LAHIJANI, J
    NYSTEN, B
    ISSI, JP
    [J]. CARBON, 1993, 31 (06) : 1001 - 1002
  • [23] RESISTIVITY OF LI-INTERCALATED PITCH-BASED CARBON-FIBER ELECTRODE MEASURED IN-SITU
    EBANA, J
    IKEZAWA, Y
    TAKAMURA, T
    [J]. DENKI KAGAKU, 1993, 61 (07): : 727 - 728
  • [24] Structure and air-oxidation behavior of the isotropic pitch-based carbon fiber
    Mizuno J.
    Morimoto M.
    Nono N.
    Sogabe T.
    [J]. Zairyo/Journal of the Society of Materials Science, Japan, 2016, 65 (06) : 437 - 442
  • [25] Creep behavior of a pitch-based carbon filament
    Kogure, K
    Sines, G
    Lavin, JG
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (01) : 46 - 50
  • [26] EFFECT OF SURFACE-TREATMENT OF PITCH-BASED CARBON-FIBER ON MECHANICAL-PROPERTIES OF POLYETHERNITRILE COMPOSITES
    ITOI, M
    YAMADA, Y
    PIPES, RB
    [J]. POLYMER COMPOSITES, 1992, 13 (01) : 15 - 29
  • [27] PROGRESS OF PITCH BASED CARBON-FIBER IN JAPAN
    OTANI, S
    OYA, A
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 78 - PETR
  • [28] HIGH-RESOLUTION SCANNING ELECTRON-MICROSCOPY OF PAN-BASED AND PITCH-BASED CARBON-FIBER
    VEZIE, DL
    ADAMS, WW
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 1990, 9 (08) : 883 - 887
  • [29] CONTROL OF TRANSVERSAL TEXTURE IN CIRCULAR MESOPHASE PITCH-BASED CARBON-FIBER USING NONCIRCULAR SPINNING NOZZLES
    MOCHIDA, I
    YOON, SH
    KORAI, Y
    [J]. JOURNAL OF MATERIALS SCIENCE, 1993, 28 (09) : 2331 - 2336
  • [30] Pitch-based carbon fiber with improved compressive strength
    Furuyama, M
    Arai, Y
    Katoh, O
    Harakawa, M
    [J]. EVOLVING TECHNOLOGIES FOR THE COMPETITIVE EDGE, BOOKS 1 AND 2, 1997, 42 : 738 - 744
12345