N-CHLORINATION OF ALIPHATIC OLIGOAMIDES AND POLYAMIDES BY TERT-BUTYL HYPOCHLORITE IN ORGANIC MEDIUM

被引：4

作者：

GIRARDON, V ^{[1
]}

TESSIER, M ^{[1
]}

MARECHAL, E ^{[1
]}

机构：

[1] UNIV PARIS 06,SYNTHESE MACROMOLEC LAB,CNRS,URA 24,F-75252 PARIS 05,FRANCE

来源：

POLYMER BULLETIN | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1007/BF00296079

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Several aliphatic oligoamides and polyamides have been chlorinated by tert-butyl hypochlorite in organic medium. Reactions were carried out in mild experimental conditions and no side reactions and degradations were observed. The influence of experimental parameters and of initial polymer structure on the conversion (alpha) has been examined. The modified polyamides were studied by SEC, chemical titration and H-1- and C-13-NMR.

引用

页码：657 / 664

页数：8

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