INTRAMOLECULAR ELECTRON-TRANSFER ACROSS POLYENEBRIDGES

被引：3
|
作者：
THOMAS, JA
JONES, CJ
HAMOR, TA
MCCLEVERTY, JA
MABBS, F
COLLISON, D
HARDING, C
机构：
[1] UNIV BRISTOL,BRISTOL BS8 1TH,AVON,ENGLAND
[2] OPEN UNIV,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND
[3] UNIV MANCHESTER,MANCHESTER M13 9PL,LANCS,ENGLAND
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1993年 / 234卷
关键词：
D O I：
10.1080/10587259308042903
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The new bipyridylpolyene bridged bimetallic complexes [{LMo(NO)Cl}NC5H5-(C2H2)n-C5H5N] (n = 2-4 all trans) have been synthesised along with their monometallic counterpart [{LMo(NO)Cl}NC5H5-(C2H2)n-C5H5N]. All of the bimetallic complexes exhibit EPR spectra consistent with fast electron exchange between the metal centres and may be reduced in two 1-electron processes, the separation between which decreases by approximately 166 mV per additional ethenyl unit.
引用
收藏
页码：103 / 108
页数：6
相关论文
共 50 条
  • [41] EFFECTS OF ANHARMONICITY ON INTRAMOLECULAR ELECTRON-TRANSFER RATES
    ISLAMPOUR, R
    LIN, SH
    CHEMICAL PHYSICS LETTERS, 1991, 179 (1-2) : 147 - 151
  • [42] INTRAMOLECULAR ELECTRON-TRANSFER IN A MOLECULAR-BEAM
    CHATTORAJ, M
    LAURSEN, SL
    PAULSON, B
    CHUNG, DD
    CLOSS, GL
    LEVY, DH
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (22): : 8778 - 8784
  • [43] PHOTOINDUCED ELECTRON-TRANSFER ACROSS MEMBRANES
    LYMAR, SV
    PARMON, VN
    ZAMARAEV, KI
    TOPICS IN CURRENT CHEMISTRY-SERIES, 1991, 159 : 1 - 65
  • [44] ELECTRON-TRANSFER ACROSS VESICLE BILAYERS
    ROBINSON, JN
    COLEHAMILTON, DJ
    CHEMICAL SOCIETY REVIEWS, 1991, 20 (01) : 49 - 94
  • [45] INTRAMOLECULAR ELECTRON-TRANSFER AND ELECTRON DELOCALIZATION IN MOLYBDOPHOSPHATE HETEROPOLY ANIONS
    BARROWS, JN
    POPE, MT
    ADVANCES IN CHEMISTRY SERIES, 1990, (226): : 403 - 417
  • [46] PHOTOINDUCED INTRAMOLECULAR ELECTRON-TRANSFER FROM NITROXYL RADICALS
    GREEN, SA
    FOX, MA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 135 - PHYS
  • [47] STRUCTURAL STUDIES OF PHOTOINDUCED INTRAMOLECULAR ELECTRON-TRANSFER IN CYCLOPENTADIENYLNITROSYLNICKEL
    CHEN, LX
    BOWMAN, MK
    WANG, ZY
    MONTANO, PA
    NORRIS, JR
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (38): : 9457 - 9464
  • [48] ACTIVATION-ENERGIES FOR AN INTRAMOLECULAR ELECTRON-TRANSFER REACTION
    BEITZ, JV
    MILLER, JR
    COHEN, H
    WIEGHARDT, K
    MEYERSTEIN, D
    INORGANIC CHEMISTRY, 1980, 19 (04) : 966 - 968
  • [49] INTRAMOLECULAR PHOTOINDUCED ELECTRON-TRANSFER FROM NITROXYL RADICALS
    GREEN, S
    FOX, MA
    JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (40): : 14752 - 14757
  • [50] INTRAMOLECULAR ELECTRON-TRANSFER THROUGH ISOMERIC FORMS OF DICYANOBENZENE
    SCHAFFER, LJ
    TAUBE, H
    JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (16): : 3669 - 3673
12345